A 4-coordinate Ru(ii) imido: Unusual geometry, synthesis, and reactivity

Amrendra K. Singh; Benjamin G. Levine; Richard J. Staples; Aaron L. Odom

doi:10.1039/c3cc46596a

A 4-coordinate Ru(ii) imido: Unusual geometry, synthesis, and reactivity

Amrendra K. Singh
, Benjamin G. Levine
, Richard J. Staples
, Aaron L. Odom

Chemistry

Michigan State University

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

A 4-coordinate Ru(ii) imido complex, Ru(NAr)(PMe₃)₃ (1), can be prepared from cis-RuCl₂(PMe₃)₄ and LiNHAr. The structure of the imido is perhaps best described as a flat-based trigonal pyramid with the imido in the equatorial plane. A possible explanation for the unusual geometry is discussed, along with some reactivity of 1.

Original language	English
Pages (from-to)	10799-10801
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	92
DOIs	https://doi.org/10.1039/c3cc46596a
State	Published - Oct 24 2013

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title = "A 4-coordinate Ru(ii) imido: Unusual geometry, synthesis, and reactivity",

abstract = "A 4-coordinate Ru(ii) imido complex, Ru(NAr)(PMe3)3 (1), can be prepared from cis-RuCl2(PMe3)4 and LiNHAr. The structure of the imido is perhaps best described as a flat-based trigonal pyramid with the imido in the equatorial plane. A possible explanation for the unusual geometry is discussed, along with some reactivity of 1.",

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T2 - Unusual geometry, synthesis, and reactivity

AU - Singh, Amrendra K.

AU - Levine, Benjamin G.

AU - Staples, Richard J.

AU - Odom, Aaron L.

PY - 2013/10/24

Y1 - 2013/10/24

N2 - A 4-coordinate Ru(ii) imido complex, Ru(NAr)(PMe3)3 (1), can be prepared from cis-RuCl2(PMe3)4 and LiNHAr. The structure of the imido is perhaps best described as a flat-based trigonal pyramid with the imido in the equatorial plane. A possible explanation for the unusual geometry is discussed, along with some reactivity of 1.

AB - A 4-coordinate Ru(ii) imido complex, Ru(NAr)(PMe3)3 (1), can be prepared from cis-RuCl2(PMe3)4 and LiNHAr. The structure of the imido is perhaps best described as a flat-based trigonal pyramid with the imido in the equatorial plane. A possible explanation for the unusual geometry is discussed, along with some reactivity of 1.

UR - https://www.scopus.com/pages/publications/84886519459

U2 - 10.1039/c3cc46596a

DO - 10.1039/c3cc46596a

M3 - Article

AN - SCOPUS:84886519459

SN - 1359-7345

VL - 49

SP - 10799

EP - 10801

JO - Chemical Communications

JF - Chemical Communications

IS - 92

ER -

A 4-coordinate Ru(ii) imido: Unusual geometry, synthesis, and reactivity

Abstract

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