A conjugate Lewis base-Brønsted acid catalyst for the sulfenylation of nitrogen containing heterocycles under mild conditions

Christopher J. Nalbandian; Eric M. Miller; Sean T. Toenjes; Jeffery L. Gustafson

doi:10.1039/c6cc09998j

A conjugate Lewis base-Brønsted acid catalyst for the sulfenylation of nitrogen containing heterocycles under mild conditions

Christopher J. Nalbandian
, Eric M. Miller
, Sean T. Toenjes
, Jeffery L. Gustafson

Chemistry

San Diego State University

Research output: Contribution to journal › Article › peer-review

70 Scopus citations

Abstract

Catalysts that contain a thiourea tethered to a carboxylic acid were found to affect the sulfenylation of indoles and other N-heterocycles on the hour time scale at room temperature. The mild nature of these conditions allowed for the incorporation of diverse functionalities into more complex heterocycles.

Original language	English
Pages (from-to)	1494-1497
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	9
DOIs	https://doi.org/10.1039/c6cc09998j
State	Published - 2017

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10.1039/c6cc09998j

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title = "A conjugate Lewis base-Br{\o}nsted acid catalyst for the sulfenylation of nitrogen containing heterocycles under mild conditions",

abstract = "Catalysts that contain a thiourea tethered to a carboxylic acid were found to affect the sulfenylation of indoles and other N-heterocycles on the hour time scale at room temperature. The mild nature of these conditions allowed for the incorporation of diverse functionalities into more complex heterocycles.",

author = "Nalbandian, \{Christopher J.\} and Miller, \{Eric M.\} and Toenjes, \{Sean T.\} and Gustafson, \{Jeffery L.\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2017",

doi = "10.1039/c6cc09998j",

language = "English",

volume = "53",

pages = "1494--1497",

journal = "Chemical Communications",

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T1 - A conjugate Lewis base-Brønsted acid catalyst for the sulfenylation of nitrogen containing heterocycles under mild conditions

AU - Nalbandian, Christopher J.

AU - Miller, Eric M.

AU - Toenjes, Sean T.

AU - Gustafson, Jeffery L.

N1 - Publisher Copyright: © The Royal Society of Chemistry.

PY - 2017

Y1 - 2017

N2 - Catalysts that contain a thiourea tethered to a carboxylic acid were found to affect the sulfenylation of indoles and other N-heterocycles on the hour time scale at room temperature. The mild nature of these conditions allowed for the incorporation of diverse functionalities into more complex heterocycles.

AB - Catalysts that contain a thiourea tethered to a carboxylic acid were found to affect the sulfenylation of indoles and other N-heterocycles on the hour time scale at room temperature. The mild nature of these conditions allowed for the incorporation of diverse functionalities into more complex heterocycles.

UR - https://www.scopus.com/pages/publications/85010866759

U2 - 10.1039/c6cc09998j

DO - 10.1039/c6cc09998j

M3 - Article

C2 - 28084476

AN - SCOPUS:85010866759

SN - 1359-7345

VL - 53

SP - 1494

EP - 1497

JO - Chemical Communications

JF - Chemical Communications

IS - 9

ER -

A conjugate Lewis base-Brønsted acid catalyst for the sulfenylation of nitrogen containing heterocycles under mild conditions

Abstract

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