A high-resolution synchrotron X-ray powder diffraction study of trans-stilbene in zeolite ZSM-5

J. B. Parise; J. A. Hriljac; D. E. Cox; D. R. Corbin; V. Ramamurthy

doi:10.1039/C39930000226

A high-resolution synchrotron X-ray powder diffraction study of trans-stilbene in zeolite ZSM-5

J. B. Parise
, J. A. Hriljac
, D. E. Cox
, D. R. Corbin
, V. Ramamurthy

Geosciences

Brookhaven National Laboratory
DuPont

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

Upon adsorption of two molecules of stilbene per unit cell, the apparent symmetry of ZSM-5 changes to tetragonal, but the true symmetry is orthorhombic with a very small difference between aand b, which becomes progressively more pronounced with b > aas the sample is cooled to 25 K; the stilbene molecule is located in the straight channels, with one phenyl ring on the mirror plane, at the intersection of the straight and sinusoidal channels.

Original language	English
Pages (from-to)	226-228
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	3
DOIs	https://doi.org/10.1039/C39930000226
State	Published - 1993

Access to Document

10.1039/C39930000226

Cite this

@article{0fac592746b64bbcae3c776d6e85d7b4,

title = "A high-resolution synchrotron X-ray powder diffraction study of trans-stilbene in zeolite ZSM-5",

abstract = "Upon adsorption of two molecules of stilbene per unit cell, the apparent symmetry of ZSM-5 changes to tetragonal, but the true symmetry is orthorhombic with a very small difference between aand b, which becomes progressively more pronounced with b > aas the sample is cooled to 25 K; the stilbene molecule is located in the straight channels, with one phenyl ring on the mirror plane, at the intersection of the straight and sinusoidal channels.",

author = "Parise, \{J. B.\} and Hriljac, \{J. A.\} and Cox, \{D. E.\} and Corbin, \{D. R.\} and V. Ramamurthy",

year = "1993",

doi = "10.1039/C39930000226",

language = "English",

pages = "226--228",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

number = "3",

}

TY - JOUR

T1 - A high-resolution synchrotron X-ray powder diffraction study of trans-stilbene in zeolite ZSM-5

AU - Parise, J. B.

AU - Hriljac, J. A.

AU - Cox, D. E.

AU - Corbin, D. R.

AU - Ramamurthy, V.

PY - 1993

Y1 - 1993

N2 - Upon adsorption of two molecules of stilbene per unit cell, the apparent symmetry of ZSM-5 changes to tetragonal, but the true symmetry is orthorhombic with a very small difference between aand b, which becomes progressively more pronounced with b > aas the sample is cooled to 25 K; the stilbene molecule is located in the straight channels, with one phenyl ring on the mirror plane, at the intersection of the straight and sinusoidal channels.

AB - Upon adsorption of two molecules of stilbene per unit cell, the apparent symmetry of ZSM-5 changes to tetragonal, but the true symmetry is orthorhombic with a very small difference between aand b, which becomes progressively more pronounced with b > aas the sample is cooled to 25 K; the stilbene molecule is located in the straight channels, with one phenyl ring on the mirror plane, at the intersection of the straight and sinusoidal channels.

UR - https://www.scopus.com/pages/publications/33845775373

U2 - 10.1039/C39930000226

DO - 10.1039/C39930000226

M3 - Article

AN - SCOPUS:33845775373

SN - 0022-4936

SP - 226

EP - 228

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 3

ER -

A high-resolution synchrotron X-ray powder diffraction study of trans-stilbene in zeolite ZSM-5

Abstract

Access to Document

Other files and links

Fingerprint

Cite this