A hydrogen-bonded dichloromethane-perchlorate-water channel in the crystal structure of cis-[Ru(bpy)2{PPh-(o-tolyl)2}Cl+][ClO 4-]·CH2Cl2·H 2O

Melvyn Rowen Churchill; Lynn M. Krajkowski; My Hang Vo Huynh; Kenneth J. Takeuchi

doi:10.1007/BF02018700

A hydrogen-bonded dichloromethane-perchlorate-water channel in the crystal structure of cis-[Ru(bpy)₂{PPh-(o-tolyl)₂}Cl⁺][ClO ₄^-]·CH₂Cl₂·H ₂O

Melvyn Rowen Churchill
, Lynn M. Krajkowski
, My Hang Vo Huynh
, Kenneth J. Takeuchi

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

The complex cis-[Ru(bpy)₂{PPh(o-tolyl)₂}Cl⁺][ClO ₄^-] crystallized from a solution in dichloromethane as the dichloromethane-water solvate. The structure was refined to R = 4.5% for those 2433 reflections with |F_o| > 6σ(|F_o|). The octahedral Ru(II) cation is associated with metal-ligand distances as follows: Ru-Cl = 2.434(3)Å, Ru-PPh(o-tol)₂ = 2.382(2)Å, and Ru-N = 2.037(7) - 2.088(7)Å. The structure is stabilized by a hydrogen-bonded CH₂Cl₂⋯ClO₄^-⋯H ₂O channel which incorporates adventitious water of crystallization.

Original language	English
Pages (from-to)	67-73
Number of pages	7
Journal	Journal of Chemical Crystallography
Volume	26
Issue number	1
DOIs	https://doi.org/10.1007/BF02018700
State	Published - Jan 1996

Keywords

Bipyridyl
Crystal structure
Hydrogen bonding
Phenyldi(o-tolyl)phosphine
Ruthenium(II)
Solvate

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10.1007/BF02018700

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@article{453430bdfc8641b5bc9f80195093ce12,

title = "A hydrogen-bonded dichloromethane-perchlorate-water channel in the crystal structure of cis-[Ru(bpy)2\{PPh-(o-tolyl)2\}Cl+][ClO 4-]·CH2Cl2·H 2O",

abstract = "The complex cis-[Ru(bpy)2\{PPh(o-tolyl)2\}Cl+][ClO 4-] crystallized from a solution in dichloromethane as the dichloromethane-water solvate. The structure was refined to R = 4.5\% for those 2433 reflections with |Fo| > 6σ(|Fo|). The octahedral Ru(II) cation is associated with metal-ligand distances as follows: Ru-Cl = 2.434(3){\AA}, Ru-PPh(o-tol)2 = 2.382(2){\AA}, and Ru-N = 2.037(7) - 2.088(7){\AA}. The structure is stabilized by a hydrogen-bonded CH2Cl2⋯ClO4-⋯H 2O channel which incorporates adventitious water of crystallization.",

keywords = "Bipyridyl, Crystal structure, Hydrogen bonding, Phenyldi(o-tolyl)phosphine, Ruthenium(II), Solvate",

author = "Churchill, \{Melvyn Rowen\} and Krajkowski, \{Lynn M.\} and Huynh, \{My Hang Vo\} and Takeuchi, \{Kenneth J.\}",

year = "1996",

month = jan,

doi = "10.1007/BF02018700",

language = "English",

volume = "26",

pages = "67--73",

journal = "Journal of Chemical Crystallography",

issn = "1074-1542",

number = "1",

}

TY - JOUR

T1 - A hydrogen-bonded dichloromethane-perchlorate-water channel in the crystal structure of cis-[Ru(bpy)2{PPh-(o-tolyl)2}Cl+][ClO 4-]·CH2Cl2·H 2O

AU - Churchill, Melvyn Rowen

AU - Krajkowski, Lynn M.

AU - Huynh, My Hang Vo

AU - Takeuchi, Kenneth J.

PY - 1996/1

Y1 - 1996/1

N2 - The complex cis-[Ru(bpy)2{PPh(o-tolyl)2}Cl+][ClO 4-] crystallized from a solution in dichloromethane as the dichloromethane-water solvate. The structure was refined to R = 4.5% for those 2433 reflections with |Fo| > 6σ(|Fo|). The octahedral Ru(II) cation is associated with metal-ligand distances as follows: Ru-Cl = 2.434(3)Å, Ru-PPh(o-tol)2 = 2.382(2)Å, and Ru-N = 2.037(7) - 2.088(7)Å. The structure is stabilized by a hydrogen-bonded CH2Cl2⋯ClO4-⋯H 2O channel which incorporates adventitious water of crystallization.

AB - The complex cis-[Ru(bpy)2{PPh(o-tolyl)2}Cl+][ClO 4-] crystallized from a solution in dichloromethane as the dichloromethane-water solvate. The structure was refined to R = 4.5% for those 2433 reflections with |Fo| > 6σ(|Fo|). The octahedral Ru(II) cation is associated with metal-ligand distances as follows: Ru-Cl = 2.434(3)Å, Ru-PPh(o-tol)2 = 2.382(2)Å, and Ru-N = 2.037(7) - 2.088(7)Å. The structure is stabilized by a hydrogen-bonded CH2Cl2⋯ClO4-⋯H 2O channel which incorporates adventitious water of crystallization.

KW - Bipyridyl

KW - Crystal structure

KW - Hydrogen bonding

KW - Phenyldi(o-tolyl)phosphine

KW - Ruthenium(II)

KW - Solvate

UR - https://www.scopus.com/pages/publications/0001911459

U2 - 10.1007/BF02018700

DO - 10.1007/BF02018700

M3 - Article

AN - SCOPUS:0001911459

SN - 1074-1542

VL - 26

SP - 67

EP - 73

JO - Journal of Chemical Crystallography

JF - Journal of Chemical Crystallography

IS - 1

ER -

A hydrogen-bonded dichloromethane-perchlorate-water channel in the crystal structure of cis-[Ru(bpy)₂{PPh-(o-tolyl)₂}Cl⁺][ClO ₄^-]·CH₂Cl₂·H ₂O

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Keywords

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