A magnesium-lithium heterometallic coordination network

Paul J. Calderone; Debasis Banerjee; Lauren A. Borkowski; John B. Parise

doi:10.1016/j.inoche.2011.02.025

A magnesium-lithium heterometallic coordination network

Paul J. Calderone
, Debasis Banerjee
, Lauren A. Borkowski
, John B. Parise

Geosciences

Stony Brook University

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

A three-dimensional magnesium-lithium coordination network, Mg ₂Li(BTC) (HBTC)(DMF)₂, (1) (BTC = 1,3,5- benzenetricarboxylate; DMF = N,N-dimethylformamide), the first example of a mixed-metal Mg-Li coordination network, is synthesized using solvothermal techniques. Structural characterization was completed using single crystal x-ray techniques while thermal properties and surface area measurements were conducted by thermogravimetric and BET analysis, respectively.

Original language	English
Pages (from-to)	741-744
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	14
Issue number	5
DOIs	https://doi.org/10.1016/j.inoche.2011.02.025
State	Published - May 2011

Keywords

Heterometallic coordination polymers
Lightweight metal centers
Metal-organic frameworks
S-block metals

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10.1016/j.inoche.2011.02.025

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title = "A magnesium-lithium heterometallic coordination network",

abstract = "A three-dimensional magnesium-lithium coordination network, Mg 2Li(BTC) (HBTC)(DMF)2, (1) (BTC = 1,3,5- benzenetricarboxylate; DMF = N,N-dimethylformamide), the first example of a mixed-metal Mg-Li coordination network, is synthesized using solvothermal techniques. Structural characterization was completed using single crystal x-ray techniques while thermal properties and surface area measurements were conducted by thermogravimetric and BET analysis, respectively.",

keywords = "Heterometallic coordination polymers, Lightweight metal centers, Metal-organic frameworks, S-block metals",

author = "Calderone, \{Paul J.\} and Debasis Banerjee and Borkowski, \{Lauren A.\} and Parise, \{John B.\}",

year = "2011",

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doi = "10.1016/j.inoche.2011.02.025",

language = "English",

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T1 - A magnesium-lithium heterometallic coordination network

AU - Calderone, Paul J.

AU - Banerjee, Debasis

AU - Borkowski, Lauren A.

AU - Parise, John B.

PY - 2011/5

Y1 - 2011/5

N2 - A three-dimensional magnesium-lithium coordination network, Mg 2Li(BTC) (HBTC)(DMF)2, (1) (BTC = 1,3,5- benzenetricarboxylate; DMF = N,N-dimethylformamide), the first example of a mixed-metal Mg-Li coordination network, is synthesized using solvothermal techniques. Structural characterization was completed using single crystal x-ray techniques while thermal properties and surface area measurements were conducted by thermogravimetric and BET analysis, respectively.

AB - A three-dimensional magnesium-lithium coordination network, Mg 2Li(BTC) (HBTC)(DMF)2, (1) (BTC = 1,3,5- benzenetricarboxylate; DMF = N,N-dimethylformamide), the first example of a mixed-metal Mg-Li coordination network, is synthesized using solvothermal techniques. Structural characterization was completed using single crystal x-ray techniques while thermal properties and surface area measurements were conducted by thermogravimetric and BET analysis, respectively.

KW - Heterometallic coordination polymers

KW - Lightweight metal centers

KW - Metal-organic frameworks

KW - S-block metals

UR - https://www.scopus.com/pages/publications/79954423122

U2 - 10.1016/j.inoche.2011.02.025

DO - 10.1016/j.inoche.2011.02.025

M3 - Article

AN - SCOPUS:79954423122

SN - 1387-7003

VL - 14

SP - 741

EP - 744

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 5

ER -

A magnesium-lithium heterometallic coordination network

Abstract

Keywords

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