A nanoscale molecular switch triggered by thermal, light, and guest perturbation

Martin B. Duriska; Suzanne M. Neville; Boujemaa Moubaraki; John D. Cashion; Gregory J. Haider; Karena W. Chapman; Cherif Balde; Jean Frangois Letard; Keith S. Murray; Cameron J. Kepert; Stuart R. Batten

doi:10.1002/anie.200805178

A nanoscale molecular switch triggered by thermal, light, and guest perturbation

Martin B. Duriska
, Suzanne M. Neville
, Boujemaa Moubaraki
, John D. Cashion
, Gregory J. Haider
, Karena W. Chapman
, Cherif Balde
, Jean Frangois Letard
, Keith S. Murray
, Cameron J. Kepert
, Stuart R. Batten

Chemistry

Monash University
Argonne National Laboratory
Institut de Chimie de la Matière Condensée de Bordeaux
The University of Sydney

Research output: Contribution to journal › Article › peer-review

170 Scopus citations

Abstract

Bottoms up! A discrete metallo-supramolecular nanoball (see picture), synthesized by using "bottom-up" methodologies, uniquely undergoes a solvent-sensitive, physically addressable electronic spin switching. The switching occurs by thermal, light, or solvent perturbation, where importantly it can be switched "on" or "off" by green or red laser irradiation, respectively.

Original language	English
Pages (from-to)	2549-2552
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	14
DOIs	https://doi.org/10.1002/anie.200805178
State	Published - Mar 23 2009

Keywords

Host-guest systems
Magnetic properties
Nanostructures
Spin crossover
Supramolecular chemistry

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10.1002/anie.200805178

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title = "A nanoscale molecular switch triggered by thermal, light, and guest perturbation",

abstract = "Bottoms up! A discrete metallo-supramolecular nanoball (see picture), synthesized by using {"}bottom-up{"} methodologies, uniquely undergoes a solvent-sensitive, physically addressable electronic spin switching. The switching occurs by thermal, light, or solvent perturbation, where importantly it can be switched {"}on{"} or {"}off{"} by green or red laser irradiation, respectively.",

keywords = "Host-guest systems, Magnetic properties, Nanostructures, Spin crossover, Supramolecular chemistry",

author = "Duriska, \{Martin B.\} and Neville, \{Suzanne M.\} and Boujemaa Moubaraki and Cashion, \{John D.\} and Haider, \{Gregory J.\} and Chapman, \{Karena W.\} and Cherif Balde and Letard, \{Jean Frangois\} and Murray, \{Keith S.\} and Kepert, \{Cameron J.\} and Batten, \{Stuart R.\}",

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T1 - A nanoscale molecular switch triggered by thermal, light, and guest perturbation

AU - Duriska, Martin B.

AU - Neville, Suzanne M.

AU - Moubaraki, Boujemaa

AU - Cashion, John D.

AU - Haider, Gregory J.

AU - Chapman, Karena W.

AU - Balde, Cherif

AU - Letard, Jean Frangois

AU - Murray, Keith S.

AU - Kepert, Cameron J.

AU - Batten, Stuart R.

PY - 2009/3/23

Y1 - 2009/3/23

N2 - Bottoms up! A discrete metallo-supramolecular nanoball (see picture), synthesized by using "bottom-up" methodologies, uniquely undergoes a solvent-sensitive, physically addressable electronic spin switching. The switching occurs by thermal, light, or solvent perturbation, where importantly it can be switched "on" or "off" by green or red laser irradiation, respectively.

AB - Bottoms up! A discrete metallo-supramolecular nanoball (see picture), synthesized by using "bottom-up" methodologies, uniquely undergoes a solvent-sensitive, physically addressable electronic spin switching. The switching occurs by thermal, light, or solvent perturbation, where importantly it can be switched "on" or "off" by green or red laser irradiation, respectively.

KW - Host-guest systems

KW - Magnetic properties

KW - Nanostructures

KW - Spin crossover

KW - Supramolecular chemistry

UR - https://www.scopus.com/pages/publications/70349783573

U2 - 10.1002/anie.200805178

DO - 10.1002/anie.200805178

M3 - Article

AN - SCOPUS:70349783573

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 14

ER -

A nanoscale molecular switch triggered by thermal, light, and guest perturbation

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Keywords

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