A nBuLi-mediated, expeditious and stereoselective ring-opening rearrangement of (arylmethylene)cyclopropane-1,1-dicarboxylates

Bao Hu; Linan Jiang; Jun Ren; Zhongwen Wang

doi:10.1002/ejoc.200901165

A nBuLi-mediated, expeditious and stereoselective ring-opening rearrangement of (arylmethylene)cyclopropane-1,1-dicarboxylates

Bao Hu
, Linan Jiang
, Jun Ren
, Zhongwen Wang

Psychiatry

Nankai University

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

We report herein an nBuLi-mediated, expeditious, ring-opening rearrangement of (arylmethylene)cyclopropane 1,1-diesters to prepare 1,3-diene derivatives with good stereo-selectivity. The reaction mechanism has also been discussed.

Original language	English
Pages (from-to)	1358-1363
Number of pages	6
Journal	European Journal of Organic Chemistry
Issue number	7
DOIs	https://doi.org/10.1002/ejoc.200901165
State	Published - Mar 2010

Keywords

1,3-dienes
Methylenecyclopropane
Rearrangement
Ring opening
Small ring systems
Strained molecules

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10.1002/ejoc.200901165

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title = "A nBuLi-mediated, expeditious and stereoselective ring-opening rearrangement of (arylmethylene)cyclopropane-1,1-dicarboxylates",

abstract = "We report herein an nBuLi-mediated, expeditious, ring-opening rearrangement of (arylmethylene)cyclopropane 1,1-diesters to prepare 1,3-diene derivatives with good stereo-selectivity. The reaction mechanism has also been discussed.",

keywords = "1,3-dienes, Methylenecyclopropane, Rearrangement, Ring opening, Small ring systems, Strained molecules",

author = "Bao Hu and Linan Jiang and Jun Ren and Zhongwen Wang",

year = "2010",

month = mar,

doi = "10.1002/ejoc.200901165",

language = "English",

pages = "1358--1363",

journal = "European Journal of Organic Chemistry",

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T1 - A nBuLi-mediated, expeditious and stereoselective ring-opening rearrangement of (arylmethylene)cyclopropane-1,1-dicarboxylates

AU - Hu, Bao

AU - Jiang, Linan

AU - Ren, Jun

AU - Wang, Zhongwen

PY - 2010/3

Y1 - 2010/3

N2 - We report herein an nBuLi-mediated, expeditious, ring-opening rearrangement of (arylmethylene)cyclopropane 1,1-diesters to prepare 1,3-diene derivatives with good stereo-selectivity. The reaction mechanism has also been discussed.

AB - We report herein an nBuLi-mediated, expeditious, ring-opening rearrangement of (arylmethylene)cyclopropane 1,1-diesters to prepare 1,3-diene derivatives with good stereo-selectivity. The reaction mechanism has also been discussed.

KW - 1,3-dienes

KW - Methylenecyclopropane

KW - Rearrangement

KW - Ring opening

KW - Small ring systems

KW - Strained molecules

UR - https://www.scopus.com/pages/publications/77149132456

U2 - 10.1002/ejoc.200901165

DO - 10.1002/ejoc.200901165

M3 - Article

AN - SCOPUS:77149132456

SN - 1434-193X

SP - 1358

EP - 1363

JO - European Journal of Organic Chemistry

JF - European Journal of Organic Chemistry

IS - 7

ER -

A nBuLi-mediated, expeditious and stereoselective ring-opening rearrangement of (arylmethylene)cyclopropane-1,1-dicarboxylates

Abstract

Keywords

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