A novel series of transition-metal chelates of diphenylphosphinothioylthiourea anion

Iwao Ojima; Toschitake Iwamoto; Takaharu Onishi; Naoki Inamoto; Kenzi Tamaru

doi:10.1039/C29690001501

A novel series of transition-metal chelates of diphenylphosphinothioylthiourea anion

Iwao Ojima
, Toschitake Iwamoto
, Takaharu Onishi
, Naoki Inamoto
, Kenzi Tamaru

Chemistry

The University of Tokyo

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

Two thiourea derivatives, 3-(diphenylphosphinothioyl)-1-phenylthiourea and 3-(diphenylphosphinothioyl)-1,1-diethylthiourea, behave as bidentate ligands towards Ni^II and Pd^II to produce new square-planar complexes, while the latter ligand gives a tetrahedral complex with Co ^II.

Original language	English
Pages (from-to)	1501-1502
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	24
DOIs	https://doi.org/10.1039/C29690001501
State	Published - 1969

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@article{0658ca80ff404ceca778af19dedbb1ab,

title = "A novel series of transition-metal chelates of diphenylphosphinothioylthiourea anion",

abstract = "Two thiourea derivatives, 3-(diphenylphosphinothioyl)-1-phenylthiourea and 3-(diphenylphosphinothioyl)-1,1-diethylthiourea, behave as bidentate ligands towards NiII and PdII to produce new square-planar complexes, while the latter ligand gives a tetrahedral complex with Co II.",

author = "Iwao Ojima and Toschitake Iwamoto and Takaharu Onishi and Naoki Inamoto and Kenzi Tamaru",

year = "1969",

doi = "10.1039/C29690001501",

language = "English",

pages = "1501--1502",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

number = "24",

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TY - JOUR

T1 - A novel series of transition-metal chelates of diphenylphosphinothioylthiourea anion

AU - Ojima, Iwao

AU - Iwamoto, Toschitake

AU - Onishi, Takaharu

AU - Inamoto, Naoki

AU - Tamaru, Kenzi

PY - 1969

Y1 - 1969

N2 - Two thiourea derivatives, 3-(diphenylphosphinothioyl)-1-phenylthiourea and 3-(diphenylphosphinothioyl)-1,1-diethylthiourea, behave as bidentate ligands towards NiII and PdII to produce new square-planar complexes, while the latter ligand gives a tetrahedral complex with Co II.

AB - Two thiourea derivatives, 3-(diphenylphosphinothioyl)-1-phenylthiourea and 3-(diphenylphosphinothioyl)-1,1-diethylthiourea, behave as bidentate ligands towards NiII and PdII to produce new square-planar complexes, while the latter ligand gives a tetrahedral complex with Co II.

UR - https://www.scopus.com/pages/publications/37049141474

U2 - 10.1039/C29690001501

DO - 10.1039/C29690001501

M3 - Article

AN - SCOPUS:37049141474

SN - 0022-4936

SP - 1501

EP - 1502

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 24

ER -

A novel series of transition-metal chelates of diphenylphosphinothioylthiourea anion

Abstract

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