Aluminium phosphate frameworks with clathrated ethylenediamine: X-ray characterization of Al3P3O11(OH)2·N2C2H8 (AIPO4-12)

John B. Parise

doi:10.1039/C39840001449

Aluminium phosphate frameworks with clathrated ethylenediamine: X-ray characterization of Al₃P₃O₁₁(OH)₂·N₂C₂H₈ (AIPO₄-12)

John B. Parise

Geosciences

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43 Scopus citations

Abstract

The structure of the AIPO₄-12 member of the open aluminophosphate frameworks consists of sheets of four-co-ordinate phosphorus and aluminium, [Al^IVP^IVO₄(OH)]⁻, alternating, along [100], with slabs of four-co-ordinate phosphorus and five-co-ordinate aluminium, [Al^V₂P^IV2O₇(OH)]⁺, to form channels in [010] and [001]; the sheets and slabs are linked via Al-O-P linkages with ethylenediamine positioned between them in a fashion suggesting its structure-directing (template) role during synthesis.

Original language	English
Pages (from-to)	1449-1450
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	21
DOIs	https://doi.org/10.1039/C39840001449
State	Published - 1984

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abstract = "The structure of the AIPO4-12 member of the open aluminophosphate frameworks consists of sheets of four-co-ordinate phosphorus and aluminium, [AlIVPIVO4(OH)]−, alternating, along [100], with slabs of four-co-ordinate phosphorus and five-co-ordinate aluminium, [AlV2PIV2O7(OH)]+, to form channels in [010] and [001]; the sheets and slabs are linked via Al-O-P linkages with ethylenediamine positioned between them in a fashion suggesting its structure-directing (template) role during synthesis.",

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T2 - X-ray characterization of Al3P3O11(OH)2·N2C2H8 (AIPO4-12)

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PY - 1984

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N2 - The structure of the AIPO4-12 member of the open aluminophosphate frameworks consists of sheets of four-co-ordinate phosphorus and aluminium, [AlIVPIVO4(OH)]−, alternating, along [100], with slabs of four-co-ordinate phosphorus and five-co-ordinate aluminium, [AlV2PIV2O7(OH)]+, to form channels in [010] and [001]; the sheets and slabs are linked via Al-O-P linkages with ethylenediamine positioned between them in a fashion suggesting its structure-directing (template) role during synthesis.

AB - The structure of the AIPO4-12 member of the open aluminophosphate frameworks consists of sheets of four-co-ordinate phosphorus and aluminium, [AlIVPIVO4(OH)]−, alternating, along [100], with slabs of four-co-ordinate phosphorus and five-co-ordinate aluminium, [AlV2PIV2O7(OH)]+, to form channels in [010] and [001]; the sheets and slabs are linked via Al-O-P linkages with ethylenediamine positioned between them in a fashion suggesting its structure-directing (template) role during synthesis.

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U2 - 10.1039/C39840001449

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JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 21

ER -

Aluminium phosphate frameworks with clathrated ethylenediamine: X-ray characterization of Al₃P₃O₁₁(OH)₂·N₂C₂H₈ (AIPO₄-12)

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