An antimony sulfide with a two-dimensional, intersecting system of channels

John B. Parise

An antimony sulfide with a two-dimensional, intersecting system of channels

John B. Parise

Geosciences

Research output: Contribution to journal › Article › peer-review

136 Scopus citations

Abstract

A novel open antimony sulfide framework of composition [Sb₃S₅]^- has been synthesized hydrothermally, in the presence of tetramethyl ammonium ions. Determination of the crystal structure demonstrates that the (Me₄N)⁺ molecules (Me, methyl) occlude a system of intersecting channels at 90° to one another. The three-dimensional framework is assembled from a new building unit, flat s-shaped buckled sheets of edge-linked 4-rings containing Sb₂S₂ moieties. These are cross-linked in two directions to form the system of channels.

Original language	English
Pages (from-to)	293-294
Number of pages	2
Journal	Science
Volume	251
Issue number	4991
State	Published - Jan 18 1991

Cite this

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title = "An antimony sulfide with a two-dimensional, intersecting system of channels",

abstract = "A novel open antimony sulfide framework of composition [Sb3S5]- has been synthesized hydrothermally, in the presence of tetramethyl ammonium ions. Determination of the crystal structure demonstrates that the (Me4N)+ molecules (Me, methyl) occlude a system of intersecting channels at 90° to one another. The three-dimensional framework is assembled from a new building unit, flat s-shaped buckled sheets of edge-linked 4-rings containing Sb2S2 moieties. These are cross-linked in two directions to form the system of channels.",

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AU - Parise, John B.

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N2 - A novel open antimony sulfide framework of composition [Sb3S5]- has been synthesized hydrothermally, in the presence of tetramethyl ammonium ions. Determination of the crystal structure demonstrates that the (Me4N)+ molecules (Me, methyl) occlude a system of intersecting channels at 90° to one another. The three-dimensional framework is assembled from a new building unit, flat s-shaped buckled sheets of edge-linked 4-rings containing Sb2S2 moieties. These are cross-linked in two directions to form the system of channels.

AB - A novel open antimony sulfide framework of composition [Sb3S5]- has been synthesized hydrothermally, in the presence of tetramethyl ammonium ions. Determination of the crystal structure demonstrates that the (Me4N)+ molecules (Me, methyl) occlude a system of intersecting channels at 90° to one another. The three-dimensional framework is assembled from a new building unit, flat s-shaped buckled sheets of edge-linked 4-rings containing Sb2S2 moieties. These are cross-linked in two directions to form the system of channels.

UR - https://www.scopus.com/pages/publications/0025925901

M3 - Article

AN - SCOPUS:0025925901

SN - 0036-8075

VL - 251

SP - 293

EP - 294

JO - Science

JF - Science

IS - 4991

ER -

An antimony sulfide with a two-dimensional, intersecting system of channels

Abstract

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