Abstract
The reaction of allyltrimethylsilane with α-keto esters in the presence of titanium tetrachloride afforded a γδ-unsaturated α-hydroxyvalerate in high yield, which with chiral α-keto esters in asymmetric synthesis gave 16-55% enantiomeric excess product.
| Original language | English |
|---|---|
| Pages (from-to) | 927-928 |
| Number of pages | 2 |
| Journal | Journal of the Chemical Society, Chemical Communications |
| Issue number | 22 |
| DOIs | |
| State | Published - 1976 |
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Dive into the research topics of 'Asymmetric addition of allyltrimethylsilane to (-)-menthyl pyruvate and phenylglyoxylate'. Together they form a unique fingerprint.Cite this
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