Atomic-scale visualization of inertial dynamics

A. M. Lindenberg; J. Larsson; K. Sokolowski-Tinten; K. J. Gaffney; C. Blome; O. Synnergren; J. Sheppard; C. Caleman; A. G. MacPhee; D. Weinstein; D. P. Lowney; T. K. Allison; T. Matthews; R. W. Falcone; A. L. Cavalieri; D. M. Fritz; S. H. Lee; P. H. Bucksbaum; D. A. Reis; J. Rudati; P. H. Fuoss; C. C. Kao; D. P. Siddons; R. Pahl; J. Als-Nielsen; S. Duesterer; R. Ischebeck; H. Schlarb; H. Schulte-Schrepping; Th Tschentscher; J. Schneider; D. Von Der Linde; O. Hignette; F. Sette; H. N. Chapman; R. W. Lee; T. N. Hansen; S. Techert; J. S. Wark; M. Bergh; G. Huldt; D. Van Der Spoel; N. Timneanu; J. Hajdu; R. A. Akre; E. Bong; P. Krejcik; J. Arthur; S. Brennan; K. Luening; J. B. Hastings

doi:10.1126/science.1107996

Atomic-scale visualization of inertial dynamics

A. M. Lindenberg
, J. Larsson
, K. Sokolowski-Tinten
, K. J. Gaffney
, C. Blome
, O. Synnergren
, J. Sheppard
, C. Caleman
, A. G. MacPhee
, D. Weinstein
, D. P. Lowney
, T. K. Allison
, T. Matthews
, R. W. Falcone
, A. L. Cavalieri
, D. M. Fritz
, S. H. Lee
, P. H. Bucksbaum
, D. A. Reis
, J. Rudati

P. H. Fuoss, C. C. Kao, D. P. Siddons, R. Pahl, J. Als-Nielsen, S. Duesterer, R. Ischebeck, H. Schlarb, H. Schulte-Schrepping, Th Tschentscher, J. Schneider, D. Von Der Linde, O. Hignette, F. Sette, H. N. Chapman, R. W. Lee, T. N. Hansen, S. Techert, J. S. Wark, M. Bergh, G. Huldt, D. Van Der Spoel, N. Timneanu, J. Hajdu, R. A. Akre, E. Bong, P. Krejcik, J. Arthur, S. Brennan, K. Luening, J. B. Hastings

Chemistry

Stanford Synchrotron Radiation Lightsource
Lund University
Friedrich Schiller University Jena
German Electron Synchrotron
University of Oxford
Uppsala University
University of California at Berkeley
University of Michigan, Ann Arbor
United States Department of Energy
Argonne National Laboratory
Brookhaven National Laboratory
The University of Chicago
University of Copenhagen
University of Duisburg-Essen
European Synchrotron Radiation Facility
Lawrence Livermore National Laboratory
Max Planck Institute for Biophysical Chemistry (Karl Friedrich Bonhoeffer Institute)
SLAC National Accelerator Laboratory

Research output: Contribution to journal › Article › peer-review

354 Scopus citations

Abstract

The motion of atoms on interatomic potential energy surfaces is fundamental to the dynamics of liquids and solids. An accelerator-based source of femtosecond x-ray pulses allowed us to follow directly atomic displacements on an optically modified energy landscape, leading eventually to the transition from crystalline solid to disordered liquid. We show that, to first order in time, the dynamics are inertial, and we place constraints on the shape and curvature of the transition-state potential energy surface. Our measurements point toward analogies between this nonequilibrium phase transition and the short-time dynamics intrinsic to equilibrium liquids.

Original language	English
Pages (from-to)	392-395
Number of pages	4
Journal	Science
Volume	308
Issue number	5720
DOIs	https://doi.org/10.1126/science.1107996
State	Published - Apr 15 2005

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Lindenberg, A. M., Larsson, J., Sokolowski-Tinten, K., Gaffney, K. J., Blome, C., Synnergren, O., Sheppard, J., Caleman, C., MacPhee, A. G., Weinstein, D., Lowney, D. P., Allison, T. K., Matthews, T., Falcone, R. W., Cavalieri, A. L., Fritz, D. M., Lee, S. H., Bucksbaum, P. H., Reis, D. A., ... Hastings, J. B. (2005). Atomic-scale visualization of inertial dynamics. Science, 308(5720), 392-395. https://doi.org/10.1126/science.1107996

@article{ac842d1876ce4b1fbe9ea1029aed23ff,

title = "Atomic-scale visualization of inertial dynamics",

abstract = "The motion of atoms on interatomic potential energy surfaces is fundamental to the dynamics of liquids and solids. An accelerator-based source of femtosecond x-ray pulses allowed us to follow directly atomic displacements on an optically modified energy landscape, leading eventually to the transition from crystalline solid to disordered liquid. We show that, to first order in time, the dynamics are inertial, and we place constraints on the shape and curvature of the transition-state potential energy surface. Our measurements point toward analogies between this nonequilibrium phase transition and the short-time dynamics intrinsic to equilibrium liquids.",

author = "Lindenberg, \{A. M.\} and J. Larsson and K. Sokolowski-Tinten and Gaffney, \{K. J.\} and C. Blome and O. Synnergren and J. Sheppard and C. Caleman and MacPhee, \{A. G.\} and D. Weinstein and Lowney, \{D. P.\} and Allison, \{T. K.\} and T. Matthews and Falcone, \{R. W.\} and Cavalieri, \{A. L.\} and Fritz, \{D. M.\} and Lee, \{S. H.\} and Bucksbaum, \{P. H.\} and Reis, \{D. A.\} and J. Rudati and Fuoss, \{P. H.\} and Kao, \{C. C.\} and Siddons, \{D. P.\} and R. Pahl and J. Als-Nielsen and S. Duesterer and R. Ischebeck and H. Schlarb and H. Schulte-Schrepping and Th Tschentscher and J. Schneider and \{Von Der Linde\}, D. and O. Hignette and F. Sette and Chapman, \{H. N.\} and Lee, \{R. W.\} and Hansen, \{T. N.\} and S. Techert and Wark, \{J. S.\} and M. Bergh and G. Huldt and \{Van Der Spoel\}, D. and N. Timneanu and J. Hajdu and Akre, \{R. A.\} and E. Bong and P. Krejcik and J. Arthur and S. Brennan and K. Luening and Hastings, \{J. B.\}",

year = "2005",

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day = "15",

doi = "10.1126/science.1107996",

language = "English",

volume = "308",

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Lindenberg, AM, Larsson, J, Sokolowski-Tinten, K, Gaffney, KJ, Blome, C, Synnergren, O, Sheppard, J, Caleman, C, MacPhee, AG, Weinstein, D, Lowney, DP, Allison, TK, Matthews, T, Falcone, RW, Cavalieri, AL, Fritz, DM, Lee, SH, Bucksbaum, PH, Reis, DA, Rudati, J, Fuoss, PH, Kao, CC, Siddons, DP, Pahl, R, Als-Nielsen, J, Duesterer, S, Ischebeck, R, Schlarb, H, Schulte-Schrepping, H, Tschentscher, T, Schneider, J, Von Der Linde, D, Hignette, O, Sette, F, Chapman, HN, Lee, RW, Hansen, TN, Techert, S, Wark, JS, Bergh, M, Huldt, G, Van Der Spoel, D, Timneanu, N, Hajdu, J, Akre, RA, Bong, E, Krejcik, P, Arthur, J, Brennan, S, Luening, K & Hastings, JB 2005, 'Atomic-scale visualization of inertial dynamics', Science, vol. 308, no. 5720, pp. 392-395. https://doi.org/10.1126/science.1107996

TY - JOUR

T1 - Atomic-scale visualization of inertial dynamics

AU - Lindenberg, A. M.

AU - Larsson, J.

AU - Sokolowski-Tinten, K.

AU - Gaffney, K. J.

AU - Blome, C.

AU - Synnergren, O.

AU - Sheppard, J.

AU - Caleman, C.

AU - MacPhee, A. G.

AU - Weinstein, D.

AU - Lowney, D. P.

AU - Allison, T. K.

AU - Matthews, T.

AU - Falcone, R. W.

AU - Cavalieri, A. L.

AU - Fritz, D. M.

AU - Lee, S. H.

AU - Bucksbaum, P. H.

AU - Reis, D. A.

AU - Rudati, J.

AU - Fuoss, P. H.

AU - Kao, C. C.

AU - Siddons, D. P.

AU - Pahl, R.

AU - Als-Nielsen, J.

AU - Duesterer, S.

AU - Ischebeck, R.

AU - Schlarb, H.

AU - Schulte-Schrepping, H.

AU - Tschentscher, Th

AU - Schneider, J.

AU - Von Der Linde, D.

AU - Hignette, O.

AU - Sette, F.

AU - Chapman, H. N.

AU - Lee, R. W.

AU - Hansen, T. N.

AU - Techert, S.

AU - Wark, J. S.

AU - Bergh, M.

AU - Huldt, G.

AU - Van Der Spoel, D.

AU - Timneanu, N.

AU - Hajdu, J.

AU - Akre, R. A.

AU - Bong, E.

AU - Krejcik, P.

AU - Arthur, J.

AU - Brennan, S.

AU - Luening, K.

AU - Hastings, J. B.

PY - 2005/4/15

Y1 - 2005/4/15

N2 - The motion of atoms on interatomic potential energy surfaces is fundamental to the dynamics of liquids and solids. An accelerator-based source of femtosecond x-ray pulses allowed us to follow directly atomic displacements on an optically modified energy landscape, leading eventually to the transition from crystalline solid to disordered liquid. We show that, to first order in time, the dynamics are inertial, and we place constraints on the shape and curvature of the transition-state potential energy surface. Our measurements point toward analogies between this nonequilibrium phase transition and the short-time dynamics intrinsic to equilibrium liquids.

AB - The motion of atoms on interatomic potential energy surfaces is fundamental to the dynamics of liquids and solids. An accelerator-based source of femtosecond x-ray pulses allowed us to follow directly atomic displacements on an optically modified energy landscape, leading eventually to the transition from crystalline solid to disordered liquid. We show that, to first order in time, the dynamics are inertial, and we place constraints on the shape and curvature of the transition-state potential energy surface. Our measurements point toward analogies between this nonequilibrium phase transition and the short-time dynamics intrinsic to equilibrium liquids.

UR - https://www.scopus.com/pages/publications/20244380030

U2 - 10.1126/science.1107996

DO - 10.1126/science.1107996

M3 - Article

C2 - 15831753

AN - SCOPUS:20244380030

SN - 0036-8075

VL - 308

SP - 392

EP - 395

JO - Science

JF - Science

IS - 5720

ER -

Atomic-scale visualization of inertial dynamics

Abstract

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