Catalytic asymmetric transformations with fine-tunable biphenol-based monodentate ligands

Bruno D. Chapsal; Zihao Hua; Iwao Ojima

doi:10.1016/j.tetasy.2005.12.035

Catalytic asymmetric transformations with fine-tunable biphenol-based monodentate ligands

Bruno D. Chapsal
, Zihao Hua
, Iwao Ojima

Chemistry

Stony Brook University

Research output: Contribution to journal › Article › peer-review

43 Scopus citations

Abstract

A library of new fine-tunable monodentate phosphite and phosphoramidite ligands based on chiral biphenol have been designed and developed. These monodentate phosphorus ligands have exhibited excellent enantioselectivity in the Pd-catalyzed asymmetric allylic alkylation and Rh-catalyzed asymmetric hydrogenation.

Original language	English
Pages (from-to)	642-657
Number of pages	16
Journal	Tetrahedron Asymmetry
Volume	17
Issue number	4
DOIs	https://doi.org/10.1016/j.tetasy.2005.12.035
State	Published - Feb 20 2006

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title = "Catalytic asymmetric transformations with fine-tunable biphenol-based monodentate ligands",

abstract = "A library of new fine-tunable monodentate phosphite and phosphoramidite ligands based on chiral biphenol have been designed and developed. These monodentate phosphorus ligands have exhibited excellent enantioselectivity in the Pd-catalyzed asymmetric allylic alkylation and Rh-catalyzed asymmetric hydrogenation.",

author = "Chapsal, \{Bruno D.\} and Zihao Hua and Iwao Ojima",

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AU - Chapsal, Bruno D.

AU - Hua, Zihao

AU - Ojima, Iwao

PY - 2006/2/20

Y1 - 2006/2/20

N2 - A library of new fine-tunable monodentate phosphite and phosphoramidite ligands based on chiral biphenol have been designed and developed. These monodentate phosphorus ligands have exhibited excellent enantioselectivity in the Pd-catalyzed asymmetric allylic alkylation and Rh-catalyzed asymmetric hydrogenation.

AB - A library of new fine-tunable monodentate phosphite and phosphoramidite ligands based on chiral biphenol have been designed and developed. These monodentate phosphorus ligands have exhibited excellent enantioselectivity in the Pd-catalyzed asymmetric allylic alkylation and Rh-catalyzed asymmetric hydrogenation.

UR - https://www.scopus.com/pages/publications/33645882256

U2 - 10.1016/j.tetasy.2005.12.035

DO - 10.1016/j.tetasy.2005.12.035

M3 - Article

AN - SCOPUS:33645882256

SN - 0957-4166

VL - 17

SP - 642

EP - 657

JO - Tetrahedron Asymmetry

JF - Tetrahedron Asymmetry

IS - 4

ER -

Catalytic asymmetric transformations with fine-tunable biphenol-based monodentate ligands

Abstract

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