Cathode dissolution as a battery failure mechanism in silver vanadium oxide (SVO) and structurally-stabilized SVO-analogue materials using phosphate (PO43-)

Rachel A. DeMayo; David C. Bock; Kenneth J. Takeuchi; Amy C. Marschilok; Esther S. Takeuchi

doi:10.1149/06609.0231ecst

Cathode dissolution as a battery failure mechanism in silver vanadium oxide (SVO) and structurally-stabilized SVO-analogue materials using phosphate (PO4^3-)

Rachel A. DeMayo
, David C. Bock
, Kenneth J. Takeuchi
, Amy C. Marschilok
, Esther S. Takeuchi

Stony Brook University

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

3 Scopus citations

Abstract

Battery failure manifested as an increase in cell impedance as a result of cathode dissolution is discussed. Analogous oxide and phosphate based materials exhibit similar electrochemical performance yet the phosphate based materials display increased structural stability and resistance to solvation formation in non-aqueous electrolytes. Structural modifications could optimize existing battery systems and address one of the main causes of increased cell impedance observed over time.

Original language	English
Title of host publication	Lithium-Ion Batteries and Beyond
Editors	K. Amine, B. L. Lucht, J. Muldoon
Publisher	Electrochemical Society Inc.
Pages	231-246
Number of pages	16
Edition	9
ISBN (Electronic)	9781607686323
DOIs	https://doi.org/10.1149/06609.0231ecst
State	Published - 2015
Event	Symposium on Lithium-Ion Batteries and Beyond - 227th ECS Meeting - Chicago, United States Duration: May 24 2015 → May 28 2015

Publication series

Name	ECS Transactions
Number	9
Volume	66
ISSN (Print)	1938-6737
ISSN (Electronic)	1938-5862

Conference

Conference	Symposium on Lithium-Ion Batteries and Beyond - 227th ECS Meeting
Country/Territory	United States
City	Chicago
Period	05/24/15 → 05/28/15

Access to Document

10.1149/06609.0231ecst

Cite this

DeMayo, R. A., Bock, D. C., Takeuchi, K. J., Marschilok, A. C., & Takeuchi, E. S. (2015). Cathode dissolution as a battery failure mechanism in silver vanadium oxide (SVO) and structurally-stabilized SVO-analogue materials using phosphate (PO4^3-). In K. Amine, B. L. Lucht, & J. Muldoon (Eds.), Lithium-Ion Batteries and Beyond (9 ed., pp. 231-246). (ECS Transactions; Vol. 66, No. 9). Electrochemical Society Inc.. https://doi.org/10.1149/06609.0231ecst

DeMayo, Rachel A. ; Bock, David C. ; Takeuchi, Kenneth J. et al. / Cathode dissolution as a battery failure mechanism in silver vanadium oxide (SVO) and structurally-stabilized SVO-analogue materials using phosphate (PO4^3-). Lithium-Ion Batteries and Beyond. editor / K. Amine ; B. L. Lucht ; J. Muldoon. 9. ed. Electrochemical Society Inc., 2015. pp. 231-246 (ECS Transactions; 9).

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title = "Cathode dissolution as a battery failure mechanism in silver vanadium oxide (SVO) and structurally-stabilized SVO-analogue materials using phosphate (PO43-)",

abstract = "Battery failure manifested as an increase in cell impedance as a result of cathode dissolution is discussed. Analogous oxide and phosphate based materials exhibit similar electrochemical performance yet the phosphate based materials display increased structural stability and resistance to solvation formation in non-aqueous electrolytes. Structural modifications could optimize existing battery systems and address one of the main causes of increased cell impedance observed over time.",

author = "DeMayo, \{Rachel A.\} and Bock, \{David C.\} and Takeuchi, \{Kenneth J.\} and Marschilok, \{Amy C.\} and Takeuchi, \{Esther S.\}",

note = "Publisher Copyright: {\textcopyright} The Electrochemical Society.; Symposium on Lithium-Ion Batteries and Beyond - 227th ECS Meeting ; Conference date: 24-05-2015 Through 28-05-2015",

year = "2015",

doi = "10.1149/06609.0231ecst",

language = "English",

series = "ECS Transactions",

publisher = "Electrochemical Society Inc.",

number = "9",

pages = "231--246",

editor = "K. Amine and Lucht, \{B. L.\} and J. Muldoon",

booktitle = "Lithium-Ion Batteries and Beyond",

edition = "9",

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DeMayo, RA, Bock, DC, Takeuchi, KJ , Marschilok, AC & Takeuchi, ES 2015, Cathode dissolution as a battery failure mechanism in silver vanadium oxide (SVO) and structurally-stabilized SVO-analogue materials using phosphate (PO4^3-). in K Amine, BL Lucht & J Muldoon (eds), Lithium-Ion Batteries and Beyond. 9 edn, ECS Transactions, no. 9, vol. 66, Electrochemical Society Inc., pp. 231-246, Symposium on Lithium-Ion Batteries and Beyond - 227th ECS Meeting, Chicago, United States, 05/24/15. https://doi.org/10.1149/06609.0231ecst

Cathode dissolution as a battery failure mechanism in silver vanadium oxide (SVO) and structurally-stabilized SVO-analogue materials using phosphate (PO4^3-). / DeMayo, Rachel A.; Bock, David C.; Takeuchi, Kenneth J. et al.
Lithium-Ion Batteries and Beyond. ed. / K. Amine; B. L. Lucht; J. Muldoon. 9. ed. Electrochemical Society Inc., 2015. p. 231-246 (ECS Transactions; Vol. 66, No. 9).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

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AU - DeMayo, Rachel A.

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AU - Takeuchi, Kenneth J.

AU - Marschilok, Amy C.

AU - Takeuchi, Esther S.

N1 - Publisher Copyright: © The Electrochemical Society.

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Y1 - 2015

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AB - Battery failure manifested as an increase in cell impedance as a result of cathode dissolution is discussed. Analogous oxide and phosphate based materials exhibit similar electrochemical performance yet the phosphate based materials display increased structural stability and resistance to solvation formation in non-aqueous electrolytes. Structural modifications could optimize existing battery systems and address one of the main causes of increased cell impedance observed over time.

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BT - Lithium-Ion Batteries and Beyond

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DeMayo RA, Bock DC, Takeuchi KJ , Marschilok AC , Takeuchi ES. Cathode dissolution as a battery failure mechanism in silver vanadium oxide (SVO) and structurally-stabilized SVO-analogue materials using phosphate (PO4^3-). In Amine K, Lucht BL, Muldoon J, editors, Lithium-Ion Batteries and Beyond. 9 ed. Electrochemical Society Inc. 2015. p. 231-246. (ECS Transactions; 9). doi: 10.1149/06609.0231ecst