Cobalt molybdenum oxynitrides: Synthesis, structural characterization, and catalytic activity for the oxygen reduction reaction

Bingfei Cao; Gabriel M. Veith; Rosa E. Diaz; Jue Liu; Eric A. Stach; Radoslav R. Adzic; Peter G. Khalifah

doi:10.1002/anie.201303197

Cobalt molybdenum oxynitrides: Synthesis, structural characterization, and catalytic activity for the oxygen reduction reaction

Bingfei Cao
, Gabriel M. Veith
, Rosa E. Diaz
, Jue Liu
, Eric A. Stach
, Radoslav R. Adzic
, Peter G. Khalifah

Chemistry

Stony Brook University
Oak Ridge National Laboratory
Brookhaven National Laboratory

Research output: Contribution to journal › Article › peer-review

148 Scopus citations

Abstract

A non-noble metal electrocatalyst has been developed for the oxygen reduction reaction. Carbon-supported cobalt molybdenum oxynitride was simply prepared by impregnation followed by thermal ammonolysis. The oxynitride electrocatalytic activity nearly matched that of platinum in 0.1 M KOH solution. The catalyst structure and valence have been characterized using complementary local and bulk probes.

Original language	English
Pages (from-to)	10753-10757
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	41
DOIs	https://doi.org/10.1002/anie.201303197
State	Published - Oct 4 2013

Keywords

electrochemistry
heterogeneous catalysis
nanoparticles
oxygen reduction
oxynitrides

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10.1002/anie.201303197

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title = "Cobalt molybdenum oxynitrides: Synthesis, structural characterization, and catalytic activity for the oxygen reduction reaction",

abstract = "A non-noble metal electrocatalyst has been developed for the oxygen reduction reaction. Carbon-supported cobalt molybdenum oxynitride was simply prepared by impregnation followed by thermal ammonolysis. The oxynitride electrocatalytic activity nearly matched that of platinum in 0.1 M KOH solution. The catalyst structure and valence have been characterized using complementary local and bulk probes.",

keywords = "electrochemistry, heterogeneous catalysis, nanoparticles, oxygen reduction, oxynitrides",

author = "Bingfei Cao and Veith, \{Gabriel M.\} and Diaz, \{Rosa E.\} and Jue Liu and Stach, \{Eric A.\} and Adzic, \{Radoslav R.\} and Khalifah, \{Peter G.\}",

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language = "English",

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T1 - Cobalt molybdenum oxynitrides

T2 - Synthesis, structural characterization, and catalytic activity for the oxygen reduction reaction

AU - Cao, Bingfei

AU - Veith, Gabriel M.

AU - Diaz, Rosa E.

AU - Liu, Jue

AU - Stach, Eric A.

AU - Adzic, Radoslav R.

AU - Khalifah, Peter G.

PY - 2013/10/4

Y1 - 2013/10/4

N2 - A non-noble metal electrocatalyst has been developed for the oxygen reduction reaction. Carbon-supported cobalt molybdenum oxynitride was simply prepared by impregnation followed by thermal ammonolysis. The oxynitride electrocatalytic activity nearly matched that of platinum in 0.1 M KOH solution. The catalyst structure and valence have been characterized using complementary local and bulk probes.

AB - A non-noble metal electrocatalyst has been developed for the oxygen reduction reaction. Carbon-supported cobalt molybdenum oxynitride was simply prepared by impregnation followed by thermal ammonolysis. The oxynitride electrocatalytic activity nearly matched that of platinum in 0.1 M KOH solution. The catalyst structure and valence have been characterized using complementary local and bulk probes.

KW - electrochemistry

KW - heterogeneous catalysis

KW - nanoparticles

KW - oxygen reduction

KW - oxynitrides

UR - https://www.scopus.com/pages/publications/84885102511

U2 - 10.1002/anie.201303197

DO - 10.1002/anie.201303197

M3 - Article

AN - SCOPUS:84885102511

SN - 1433-7851

VL - 52

SP - 10753

EP - 10757

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 41

ER -

Cobalt molybdenum oxynitrides: Synthesis, structural characterization, and catalytic activity for the oxygen reduction reaction

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Keywords

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