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Communication: Classical threshold law for ion-neutral-neutral three-body recombination

  • Purdue University

Research output: Contribution to journalArticlepeer-review

43 Scopus citations

Abstract

A very recently method for classical trajectory calculations for three-body collision [Pérez-Ríos et al., J. Chem. Phys. 140, 044307 (2014)] has been applied to describe ion-neutral-neutral ternary processes for low energy collisions: 0.1 mK-10 mK. As a result, a threshold law for the three-body recombination cross section is obtained and corroborated numerically. The derived threshold law predicts the formation of weakly bound dimers, with binding energies comparable to the collision energy of the collisional partners. In this low energy range, this analysis predicts that molecular ions should dominate over molecular neutrals as the most products formed.

Original languageEnglish
Article number041105
JournalJournal of Chemical Physics
Volume143
Issue number4
DOIs
StatePublished - Jul 28 2015

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