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Comparative resin kinetics using in situ fluorescence measurements

  • Daniel P. Walsh
  • , Christopher Pang
  • , Puja B. Parikh
  • , Young Soo Kim
  • , Young Tae Chang
  • New York University

Research output: Contribution to journalArticlepeer-review

18 Scopus citations

Abstract

The aminolysis of a novel activated ester resin was utilized for kinetic study via continuous in situ fluorescence measurements. A variety of resin compositions (polystyrene, JandaJel, ArgoPore, TentaGel, NovaGel, and PEGA) and solvents (dimethylformamide, acetonitrile, tetrahydrofuran, 1,2-dichlorethane, and toluene) were tested to compare their effects on the reaction rate. A linear relationship between the reaction rate and (solvent polarity x swelling of resin) was elucidated for the aminolysis reaction.

Original languageEnglish
Pages (from-to)204-208
Number of pages5
JournalJournal of Combinatorial Chemistry
Volume4
Issue number3
DOIs
StatePublished - May 2002

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