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Comparison of classical and quantal calculations of helium three-body recombination

  • University of Maryland, College Park
  • University of Connecticut
  • Purdue University

Research output: Contribution to journalArticlepeer-review

52 Scopus citations

Abstract

A general method to study classical scattering in n-dimension is developed. Through classical trajectory calculations, the three-body recombination is computed as a function of the collision energy for helium atoms, as an example. Quantum calculations are also performed for the JΠ = 0+ symmetry of the three-body recombination rate in order to compare with the classical results, yielding good agreement for E ≳ 1 K. The classical threshold law is derived and numerically confirmed for the Newtonian three-body recombination rate. Finally, a relationship is found between the quantum and classical three-body hard hypersphere elastic cross sections which is analogous to the well-known shadow scattering in two-body collisions.

Original languageEnglish
Article number044307
JournalJournal of Chemical Physics
Volume140
Issue number4
DOIs
StatePublished - Jan 28 2014

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