Convenient synthetic routes to the cyclopentadienylruthenium dicarbonyl chloride and bromide

Amihai Eisenstadt; Rina Tannenbaum; Avi Efraty

doi:10.1016/S0022-328X(00)88373-4

Convenient synthetic routes to the cyclopentadienylruthenium dicarbonyl chloride and bromide

Amihai Eisenstadt
, Rina Tannenbaum
, Avi Efraty

Materials Science and Engineering

Weizmann Institute of Science

Research output: Contribution to journal › Article › peer-review

39 Scopus citations

Abstract

The reactions of [CpRu(CO)₂]₂ with CX₄ (X = Cl, Br) were found to take place under indoor light conditions as well as in the dark to afford CpRu(CO)₂X (X = Cl, Br) in excellent yields. Another convenient synthetic route to such ruthenium halide complexes involves the reaction of CpRu(CO)₂H, prepared "in situ" from Ru₃(CO)₁₂ and cyclopentadiene, with CX₄ (X = Cl, Br).

Original language	English
Pages (from-to)	317-321
Number of pages	5
Journal	Journal of Organometallic Chemistry
Volume	221
Issue number	3
DOIs	https://doi.org/10.1016/S0022-328X(00)88373-4
State	Published - Dec 8 1981

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title = "Convenient synthetic routes to the cyclopentadienylruthenium dicarbonyl chloride and bromide",

abstract = "The reactions of [CpRu(CO)2]2 with CX4 (X = Cl, Br) were found to take place under indoor light conditions as well as in the dark to afford CpRu(CO)2X (X = Cl, Br) in excellent yields. Another convenient synthetic route to such ruthenium halide complexes involves the reaction of CpRu(CO)2H, prepared {"}in situ{"} from Ru3(CO)12 and cyclopentadiene, with CX4 (X = Cl, Br).",

author = "Amihai Eisenstadt and Rina Tannenbaum and Avi Efraty",

year = "1981",

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T1 - Convenient synthetic routes to the cyclopentadienylruthenium dicarbonyl chloride and bromide

AU - Eisenstadt, Amihai

AU - Tannenbaum, Rina

AU - Efraty, Avi

PY - 1981/12/8

Y1 - 1981/12/8

N2 - The reactions of [CpRu(CO)2]2 with CX4 (X = Cl, Br) were found to take place under indoor light conditions as well as in the dark to afford CpRu(CO)2X (X = Cl, Br) in excellent yields. Another convenient synthetic route to such ruthenium halide complexes involves the reaction of CpRu(CO)2H, prepared "in situ" from Ru3(CO)12 and cyclopentadiene, with CX4 (X = Cl, Br).

AB - The reactions of [CpRu(CO)2]2 with CX4 (X = Cl, Br) were found to take place under indoor light conditions as well as in the dark to afford CpRu(CO)2X (X = Cl, Br) in excellent yields. Another convenient synthetic route to such ruthenium halide complexes involves the reaction of CpRu(CO)2H, prepared "in situ" from Ru3(CO)12 and cyclopentadiene, with CX4 (X = Cl, Br).

UR - https://www.scopus.com/pages/publications/0000857346

U2 - 10.1016/S0022-328X(00)88373-4

DO - 10.1016/S0022-328X(00)88373-4

M3 - Article

AN - SCOPUS:0000857346

SN - 0022-328X

VL - 221

SP - 317

EP - 321

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 3

ER -

Convenient synthetic routes to the cyclopentadienylruthenium dicarbonyl chloride and bromide

Abstract

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