Correlating structure and chemistry through simultaneous in situ pair distribution function and infrared spectroscopy measurements

Karena W. Chapman; Kevin A. Beyer; Haiyan Zhao; Peter J. Chupas

doi:10.1039/c3ce41458b

Correlating structure and chemistry through simultaneous in situ pair distribution function and infrared spectroscopy measurements

Karena W. Chapman
, Kevin A. Beyer
, Haiyan Zhao
, Peter J. Chupas

Chemistry

United States Department of Energy

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

Desorption of coordinated and non-coordinated guests from the nanoporous Prussian blue analogue Mn^II₃[Co^III(CN) ₆]₂(H₂O)₆â̂™ x{H₂O} was probed by simultaneous pair distribution function and infrared spectroscopy measurements. The combined data shows how the release of guests from different sites is coupled to structural relaxation of the framework.

Original language	English
Pages (from-to)	9377-9381
Number of pages	5
Journal	CrystEngComm
Volume	15
Issue number	45
DOIs	https://doi.org/10.1039/c3ce41458b
State	Published - Dec 7 2013

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title = "Correlating structure and chemistry through simultaneous in situ pair distribution function and infrared spectroscopy measurements",

abstract = "Desorption of coordinated and non-coordinated guests from the nanoporous Prussian blue analogue MnII3[CoIII(CN) 6]2(H2O)6{\^a}̂{\texttrademark} x\{H2O\} was probed by simultaneous pair distribution function and infrared spectroscopy measurements. The combined data shows how the release of guests from different sites is coupled to structural relaxation of the framework.",

author = "Chapman, \{Karena W.\} and Beyer, \{Kevin A.\} and Haiyan Zhao and Chupas, \{Peter J.\}",

year = "2013",

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doi = "10.1039/c3ce41458b",

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T1 - Correlating structure and chemistry through simultaneous in situ pair distribution function and infrared spectroscopy measurements

AU - Chapman, Karena W.

AU - Beyer, Kevin A.

AU - Zhao, Haiyan

AU - Chupas, Peter J.

PY - 2013/12/7

Y1 - 2013/12/7

N2 - Desorption of coordinated and non-coordinated guests from the nanoporous Prussian blue analogue MnII3[CoIII(CN) 6]2(H2O)6â̂™ x{H2O} was probed by simultaneous pair distribution function and infrared spectroscopy measurements. The combined data shows how the release of guests from different sites is coupled to structural relaxation of the framework.

AB - Desorption of coordinated and non-coordinated guests from the nanoporous Prussian blue analogue MnII3[CoIII(CN) 6]2(H2O)6â̂™ x{H2O} was probed by simultaneous pair distribution function and infrared spectroscopy measurements. The combined data shows how the release of guests from different sites is coupled to structural relaxation of the framework.

UR - https://www.scopus.com/pages/publications/84886992321

U2 - 10.1039/c3ce41458b

DO - 10.1039/c3ce41458b

M3 - Article

AN - SCOPUS:84886992321

SN - 1466-8033

VL - 15

SP - 9377

EP - 9381

JO - CrystEngComm

JF - CrystEngComm

IS - 45

ER -

Correlating structure and chemistry through simultaneous in situ pair distribution function and infrared spectroscopy measurements

Abstract

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