Crystal structure of cis-[Ru(bpy)2{PPh2(o-tol)}Cl][ClO4] · 1.5(CH2Cl2), a structure containing both ordered and disordered dichloromethane molecules of crystallization

Melvyn Rowen Churchill; Lynn M. Krajkowski; My Hang Vo Huynh; Kenneth J. Takeuchi

doi:10.1007/BF01669726

Crystal structure of cis-[Ru(bpy)₂{PPh₂(o-tol)}Cl][ClO₄] · 1.5(CH₂Cl₂), a structure containing both ordered and disordered dichloromethane molecules of crystallization

Melvyn Rowen Churchill
, Lynn M. Krajkowski
, My Hang Vo Huynh
, Kenneth J. Takeuchi

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

The complex cis-[Ru(bpy)₂ {PPh₂(o-tol)}Cl][ClO₄] crystallizes from dichloromethane as the sesqui-dichloromethane solvate. The complex crystallizes in the monoclinic space group P2₁/n with Z = 4. The structure was refined to R = 5.50% for those 2552 independent reflections with |F₀| > 6σ(|F₀|). The octahedral Ru(II) cation is associated with the following bond lengths: Ru-PPh₂(o-tol) = 2.360(3)Å, Ru-Cl = 2.433(2)Å and Ru-N(bpy) = 2.041(8)-2.095(8)Å.Both the perchlorate anion and the dichloromethane molecules of solvation exhibit large amplitudes of vibration. One dichloromethane molecule lies in a general position, the other lies about an inversion center and suffers from disorder.

Original language	English
Pages (from-to)	111-116
Number of pages	6
Journal	Journal of Chemical Crystallography
Volume	26
Issue number	2
DOIs	https://doi.org/10.1007/BF01669726
State	Published - Feb 1996

Keywords

Bipyridyl
Crystal structure
Dichloromethane solvate
Diphenyl(o-tolyl)phosphine
Ruthenium(II) complex

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10.1007/BF01669726

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@article{c7e360ddb8304b538fb7377e1c4aee8e,

title = "Crystal structure of cis-[Ru(bpy)2\{PPh2(o-tol)\}Cl][ClO4] · 1.5(CH2Cl2), a structure containing both ordered and disordered dichloromethane molecules of crystallization",

abstract = "The complex cis-[Ru(bpy)2 \{PPh2(o-tol)\}Cl][ClO4] crystallizes from dichloromethane as the sesqui-dichloromethane solvate. The complex crystallizes in the monoclinic space group P21/n with Z = 4. The structure was refined to R = 5.50\% for those 2552 independent reflections with |F0| > 6σ(|F0|). The octahedral Ru(II) cation is associated with the following bond lengths: Ru-PPh2(o-tol) = 2.360(3){\AA}, Ru-Cl = 2.433(2){\AA} and Ru-N(bpy) = 2.041(8)-2.095(8){\AA}.Both the perchlorate anion and the dichloromethane molecules of solvation exhibit large amplitudes of vibration. One dichloromethane molecule lies in a general position, the other lies about an inversion center and suffers from disorder.",

keywords = "Bipyridyl, Crystal structure, Dichloromethane solvate, Diphenyl(o-tolyl)phosphine, Ruthenium(II) complex",

author = "Churchill, \{Melvyn Rowen\} and Krajkowski, \{Lynn M.\} and Huynh, \{My Hang Vo\} and Takeuchi, \{Kenneth J.\}",

year = "1996",

month = feb,

doi = "10.1007/BF01669726",

language = "English",

volume = "26",

pages = "111--116",

journal = "Journal of Chemical Crystallography",

issn = "1074-1542",

number = "2",

}

Crystal structure of cis-[Ru(bpy)₂{PPh₂(o-tol)}Cl][ClO₄] · 1.5(CH₂Cl₂), a structure containing both ordered and disordered dichloromethane molecules of crystallization. / Churchill, Melvyn Rowen; Krajkowski, Lynn M.; Huynh, My Hang Vo et al.
In: Journal of Chemical Crystallography, Vol. 26, No. 2, 02.1996, p. 111-116.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Crystal structure of cis-[Ru(bpy)2{PPh2(o-tol)}Cl][ClO4] · 1.5(CH2Cl2), a structure containing both ordered and disordered dichloromethane molecules of crystallization

AU - Churchill, Melvyn Rowen

AU - Krajkowski, Lynn M.

AU - Huynh, My Hang Vo

AU - Takeuchi, Kenneth J.

PY - 1996/2

Y1 - 1996/2

N2 - The complex cis-[Ru(bpy)2 {PPh2(o-tol)}Cl][ClO4] crystallizes from dichloromethane as the sesqui-dichloromethane solvate. The complex crystallizes in the monoclinic space group P21/n with Z = 4. The structure was refined to R = 5.50% for those 2552 independent reflections with |F0| > 6σ(|F0|). The octahedral Ru(II) cation is associated with the following bond lengths: Ru-PPh2(o-tol) = 2.360(3)Å, Ru-Cl = 2.433(2)Å and Ru-N(bpy) = 2.041(8)-2.095(8)Å.Both the perchlorate anion and the dichloromethane molecules of solvation exhibit large amplitudes of vibration. One dichloromethane molecule lies in a general position, the other lies about an inversion center and suffers from disorder.

AB - The complex cis-[Ru(bpy)2 {PPh2(o-tol)}Cl][ClO4] crystallizes from dichloromethane as the sesqui-dichloromethane solvate. The complex crystallizes in the monoclinic space group P21/n with Z = 4. The structure was refined to R = 5.50% for those 2552 independent reflections with |F0| > 6σ(|F0|). The octahedral Ru(II) cation is associated with the following bond lengths: Ru-PPh2(o-tol) = 2.360(3)Å, Ru-Cl = 2.433(2)Å and Ru-N(bpy) = 2.041(8)-2.095(8)Å.Both the perchlorate anion and the dichloromethane molecules of solvation exhibit large amplitudes of vibration. One dichloromethane molecule lies in a general position, the other lies about an inversion center and suffers from disorder.

KW - Bipyridyl

KW - Crystal structure

KW - Dichloromethane solvate

KW - Diphenyl(o-tolyl)phosphine

KW - Ruthenium(II) complex

UR - https://www.scopus.com/pages/publications/0001816826

U2 - 10.1007/BF01669726

DO - 10.1007/BF01669726

M3 - Article

AN - SCOPUS:0001816826

SN - 1074-1542

VL - 26

SP - 111

EP - 116

JO - Journal of Chemical Crystallography

JF - Journal of Chemical Crystallography

IS - 2

ER -

Crystal structure of cis-[Ru(bpy)₂{PPh₂(o-tol)}Cl][ClO₄] · 1.5(CH₂Cl₂), a structure containing both ordered and disordered dichloromethane molecules of crystallization

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