Crystal structure of the hemitoluene solvate of racemic cis-bis(bipyridyl)chloro(tri-n-propylphosphine)ruthenium(II) perchlorate, a species with disordered PPr3 and toluene moieties

Melvyn Rowen Churchill; Ronald F. See; Carol A. Bessel; Kenneth J. Takeuchi

doi:10.1007/BF01991962

Crystal structure of the hemitoluene solvate of racemic cis-bis(bipyridyl)chloro(tri-n-propylphosphine)ruthenium(II) perchlorate, a species with disordered PPr₃ and toluene moieties

Melvyn Rowen Churchill
, Ronald F. See
, Carol A. Bessel
, Kenneth J. Takeuchi

Chemistry

SUNY Buffalo
Saint Louis University
Villanova University

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The complex cis-[Ru(bpy)₂(PPr₃)Cl⁺][ClO^- ₄] · 0.5 (toluene) crystallizes as a racemate in the monoclinic space group P2₁/n. Both the PPr₃ ligand and the toluene of crystallization are subject to disorder. Ruthenium-ligand distances are: Ru-PPr₃ = 2.348(2) Å, Ru-Cl = 2.426(2) Å and Ru-N(bpy) = 2.035(6)-2.112(5) Å.

Original language	English
Pages (from-to)	667-675
Number of pages	9
Journal	Journal of Chemical Crystallography
Volume	26
Issue number	10
DOIs	https://doi.org/10.1007/BF01991962
State	Published - Oct 1996

Keywords

Bipyridyl
Crystal structure
Disorder
Ruthenium(II) complex
Tri-n-propylphosphine

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10.1007/BF01991962

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@article{3f6e266c0bdc401884dffd97d5017caa,

title = "Crystal structure of the hemitoluene solvate of racemic cis-bis(bipyridyl)chloro(tri-n-propylphosphine)ruthenium(II) perchlorate, a species with disordered PPr3 and toluene moieties",

abstract = "The complex cis-[Ru(bpy)2(PPr3)Cl+][ClO- 4] · 0.5 (toluene) crystallizes as a racemate in the monoclinic space group P21/n. Both the PPr3 ligand and the toluene of crystallization are subject to disorder. Ruthenium-ligand distances are: Ru-PPr3 = 2.348(2) {\AA}, Ru-Cl = 2.426(2) {\AA} and Ru-N(bpy) = 2.035(6)-2.112(5) {\AA}.",

keywords = "Bipyridyl, Crystal structure, Disorder, Ruthenium(II) complex, Tri-n-propylphosphine",

author = "Churchill, \{Melvyn Rowen\} and See, \{Ronald F.\} and Bessel, \{Carol A.\} and Takeuchi, \{Kenneth J.\}",

year = "1996",

month = oct,

doi = "10.1007/BF01991962",

language = "English",

volume = "26",

pages = "667--675",

journal = "Journal of Chemical Crystallography",

issn = "1074-1542",

number = "10",

}

Crystal structure of the hemitoluene solvate of racemic cis-bis(bipyridyl)chloro(tri-n-propylphosphine)ruthenium(II) perchlorate, a species with disordered PPr₃ and toluene moieties. / Churchill, Melvyn Rowen; See, Ronald F.; Bessel, Carol A. et al.
In: Journal of Chemical Crystallography, Vol. 26, No. 10, 10.1996, p. 667-675.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Crystal structure of the hemitoluene solvate of racemic cis-bis(bipyridyl)chloro(tri-n-propylphosphine)ruthenium(II) perchlorate, a species with disordered PPr3 and toluene moieties

AU - Churchill, Melvyn Rowen

AU - See, Ronald F.

AU - Bessel, Carol A.

AU - Takeuchi, Kenneth J.

PY - 1996/10

Y1 - 1996/10

N2 - The complex cis-[Ru(bpy)2(PPr3)Cl+][ClO- 4] · 0.5 (toluene) crystallizes as a racemate in the monoclinic space group P21/n. Both the PPr3 ligand and the toluene of crystallization are subject to disorder. Ruthenium-ligand distances are: Ru-PPr3 = 2.348(2) Å, Ru-Cl = 2.426(2) Å and Ru-N(bpy) = 2.035(6)-2.112(5) Å.

AB - The complex cis-[Ru(bpy)2(PPr3)Cl+][ClO- 4] · 0.5 (toluene) crystallizes as a racemate in the monoclinic space group P21/n. Both the PPr3 ligand and the toluene of crystallization are subject to disorder. Ruthenium-ligand distances are: Ru-PPr3 = 2.348(2) Å, Ru-Cl = 2.426(2) Å and Ru-N(bpy) = 2.035(6)-2.112(5) Å.

KW - Bipyridyl

KW - Crystal structure

KW - Disorder

KW - Ruthenium(II) complex

KW - Tri-n-propylphosphine

UR - https://www.scopus.com/pages/publications/0030373392

U2 - 10.1007/BF01991962

DO - 10.1007/BF01991962

M3 - Article

AN - SCOPUS:0030373392

SN - 1074-1542

VL - 26

SP - 667

EP - 675

JO - Journal of Chemical Crystallography

JF - Journal of Chemical Crystallography

IS - 10

ER -

Crystal structure of the hemitoluene solvate of racemic cis-bis(bipyridyl)chloro(tri-n-propylphosphine)ruthenium(II) perchlorate, a species with disordered PPr₃ and toluene moieties

Abstract

Keywords

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