Dehydration of the nanoporous coordination framework Er III[CoIII(CN)6]·4(H2O): Single crystal to single crystal transformation and negative thermal expansion in ErIII[CoIII(CN)6]

Thorsten Pretsch; Karena W. Chapman; Gregory J. Halder; Cameron J. Kepert

doi:10.1039/b601344a

Dehydration of the nanoporous coordination framework Er ^III[Co^III(CN)₆]·4(H₂O): Single crystal to single crystal transformation and negative thermal expansion in Er^III[Co^III(CN)₆]

Thorsten Pretsch
, Karena W. Chapman
, Gregory J. Halder
, Cameron J. Kepert

Chemistry

The University of Sydney

Research output: Contribution to journal › Article › peer-review

72 Scopus citations

Abstract

Desorption of bound and unbound water molecules from the nanoporous coordination framework Er^III[Co^III(CN)₆] ·4H₂O to form the apohost, Er^III[Co ^III(CN)₆], proceeds via a single crystal to single crystal transformation in which the Er(iii) cations change from 8- to 6-coordinate; dehydration results in a striking change in the thermal expansion properties.

Original language	English
Pages (from-to)	1857-1859
Number of pages	3
Journal	Chemical Communications
Issue number	17
DOIs	https://doi.org/10.1039/b601344a
State	Published - 2006

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10.1039/b601344a

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@article{69d92aa2c40d4e64b8dd7c6fe4179984,

title = "Dehydration of the nanoporous coordination framework Er III[CoIII(CN)6]·4(H2O): Single crystal to single crystal transformation and negative thermal expansion in ErIII[CoIII(CN)6]",

abstract = "Desorption of bound and unbound water molecules from the nanoporous coordination framework ErIII[CoIII(CN)6] ·4H2O to form the apohost, ErIII[Co III(CN)6], proceeds via a single crystal to single crystal transformation in which the Er(iii) cations change from 8- to 6-coordinate; dehydration results in a striking change in the thermal expansion properties.",

author = "Thorsten Pretsch and Chapman, \{Karena W.\} and Halder, \{Gregory J.\} and Kepert, \{Cameron J.\}",

year = "2006",

doi = "10.1039/b601344a",

language = "English",

pages = "1857--1859",

journal = "Chemical Communications",

issn = "1359-7345",

number = "17",

}

Dehydration of the nanoporous coordination framework Er ^III[Co^III(CN)₆]·4(H₂O): Single crystal to single crystal transformation and negative thermal expansion in Er^III[Co^III(CN)₆]. / Pretsch, Thorsten; Chapman, Karena W.; Halder, Gregory J. et al.
In: Chemical Communications, No. 17, 2006, p. 1857-1859.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Dehydration of the nanoporous coordination framework Er III[CoIII(CN)6]·4(H2O)

T2 - Single crystal to single crystal transformation and negative thermal expansion in ErIII[CoIII(CN)6]

AU - Pretsch, Thorsten

AU - Chapman, Karena W.

AU - Halder, Gregory J.

AU - Kepert, Cameron J.

PY - 2006

Y1 - 2006

N2 - Desorption of bound and unbound water molecules from the nanoporous coordination framework ErIII[CoIII(CN)6] ·4H2O to form the apohost, ErIII[Co III(CN)6], proceeds via a single crystal to single crystal transformation in which the Er(iii) cations change from 8- to 6-coordinate; dehydration results in a striking change in the thermal expansion properties.

AB - Desorption of bound and unbound water molecules from the nanoporous coordination framework ErIII[CoIII(CN)6] ·4H2O to form the apohost, ErIII[Co III(CN)6], proceeds via a single crystal to single crystal transformation in which the Er(iii) cations change from 8- to 6-coordinate; dehydration results in a striking change in the thermal expansion properties.

UR - https://www.scopus.com/pages/publications/33646921722

U2 - 10.1039/b601344a

DO - 10.1039/b601344a

M3 - Article

AN - SCOPUS:33646921722

SN - 1359-7345

SP - 1857

EP - 1859

JO - Chemical Communications

JF - Chemical Communications

IS - 17

ER -

Dehydration of the nanoporous coordination framework Er ^III[Co^III(CN)₆]·4(H₂O): Single crystal to single crystal transformation and negative thermal expansion in Er^III[Co^III(CN)₆]

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