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Demonstration of a pilot-scale membrane reactor process for hydrogen production

  • RTI International
  • Danaher Corporation

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

5 Scopus citations

Abstract

High performance, high-temperature hydrogen separation membranes represent a key enabling technology for efficient hydrogen production using synthesis gas derived from a variety of feedstocks. RTI International and Pall Corporation are developing high flux and selectivity hydrogen separation membranes by depositing thin Pd-alloy films on tubular ceramic/porous stainless steel composite substrates. Both the plating parameters and the inorganic substrate characteristics are being optimized for high hydrogen selectivity and membrane flux. The developmental Pd-alloy composite membranes were used in a membrane reactor configuration in a pilot-scale module for demonstrating water gas shift (WGS) reaction with simultaneous hydrogen separation producing high purity hydrogen from simulated synthesis gas. Substantially increased CO conversion was observed because of simultaneous hydrogen separation as predicted by membrane reactor model. Greater than 80% of maximum possible hydrogen was recovered in the product stream in membrane reactor operations at 375 and 550°C temperature and 100 and 150 psig pressure.

Original languageEnglish
Title of host publicationECS Transactions - Fuel Cell Seminar 2007
PublisherElectrochemical Society Inc.
Pages499-510
Number of pages12
Edition1
ISBN (Electronic)9781566776394
ISBN (Print)9781566776394
DOIs
StatePublished - 2008
EventFuel Cell Seminar 2007 - San Antonio, TX, United States
Duration: Oct 15 2007Oct 19 2007

Publication series

NameECS Transactions
Number1
Volume12
ISSN (Print)1938-5862
ISSN (Electronic)1938-6737

Conference

ConferenceFuel Cell Seminar 2007
Country/TerritoryUnited States
CitySan Antonio, TX
Period10/15/0710/19/07

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