Direct β-Selective Hydrocarboxylation of Styrenes with CO2 Enabled by Continuous Flow Photoredox Catalysis

Hyowon Seo; Aofei Liu; Timothy F. Jamison

doi:10.1021/jacs.7b05942

Direct β-Selective Hydrocarboxylation of Styrenes with CO₂ Enabled by Continuous Flow Photoredox Catalysis

Hyowon Seo
, Aofei Liu
, Timothy F. Jamison

Materials Science and Engineering

Massachusetts Institute of Technology

Research output: Contribution to journal › Article › peer-review

246 Scopus citations

Abstract

The direct β-selective hydrocarboxylation of styrenes under atmospheric pressure of CO₂ has been developed using photoredox catalysis in continuous flow. The scope of this methodology was demonstrated with a range of functionalized terminal styrenes, as well as α-substituted and β-substituted styrenes.

Original language	English
Pages (from-to)	13969-13972
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	139
Issue number	40
DOIs	https://doi.org/10.1021/jacs.7b05942
State	Published - Oct 11 2017

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title = "Direct β-Selective Hydrocarboxylation of Styrenes with CO2 Enabled by Continuous Flow Photoredox Catalysis",

abstract = "The direct β-selective hydrocarboxylation of styrenes under atmospheric pressure of CO2 has been developed using photoredox catalysis in continuous flow. The scope of this methodology was demonstrated with a range of functionalized terminal styrenes, as well as α-substituted and β-substituted styrenes.",

author = "Hyowon Seo and Aofei Liu and Jamison, \{Timothy F.\}",

note = "Publisher Copyright: {\textcopyright} 2017 American Chemical Society.",

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T1 - Direct β-Selective Hydrocarboxylation of Styrenes with CO2 Enabled by Continuous Flow Photoredox Catalysis

AU - Seo, Hyowon

AU - Liu, Aofei

AU - Jamison, Timothy F.

PY - 2017/10/11

Y1 - 2017/10/11

N2 - The direct β-selective hydrocarboxylation of styrenes under atmospheric pressure of CO2 has been developed using photoredox catalysis in continuous flow. The scope of this methodology was demonstrated with a range of functionalized terminal styrenes, as well as α-substituted and β-substituted styrenes.

AB - The direct β-selective hydrocarboxylation of styrenes under atmospheric pressure of CO2 has been developed using photoredox catalysis in continuous flow. The scope of this methodology was demonstrated with a range of functionalized terminal styrenes, as well as α-substituted and β-substituted styrenes.

UR - https://www.scopus.com/pages/publications/85031089646

U2 - 10.1021/jacs.7b05942

DO - 10.1021/jacs.7b05942

M3 - Article

C2 - 28953365

AN - SCOPUS:85031089646

SN - 0002-7863

VL - 139

SP - 13969

EP - 13972

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 40

ER -

Direct β-Selective Hydrocarboxylation of Styrenes with CO₂ Enabled by Continuous Flow Photoredox Catalysis

Abstract

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