Direct observation of adsorbed H2-framework interactions in the Prussian Blue analogue MnII3[CoIII(CN) 6]2: The relative importance of accessible coordination sites and van der Waals interactions

Karena W. Chapman; Peter J. Chupas; Evan R. Maxey; James W. Richardson

doi:10.1039/b607250j

Direct observation of adsorbed H₂-framework interactions in the Prussian Blue analogue Mn^II₃[Co^III(CN) ₆]₂: The relative importance of accessible coordination sites and van der Waals interactions

Karena W. Chapman
, Peter J. Chupas
, Evan R. Maxey
, James W. Richardson

Chemistry

United States Department of Energy
Argonne National Laboratory

Research output: Contribution to journal › Article › peer-review

70 Scopus citations

Abstract

Selective recovery of the guest-framework interactions for H₂ adsorbed in a nanoporous Prussian Blue analogue, through differential X-ray and neutron pair distribution function analysis at ca. 77 K, suggests that the H₂ molecule is disordered about a single position at the centre of the pore, (1/4,1/4,1/4), without binding at accessible Mn^II sites.

Original language	English
Pages (from-to)	4013-4015
Number of pages	3
Journal	Chemical Communications
Issue number	38
DOIs	https://doi.org/10.1039/b607250j
State	Published - 2006

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10.1039/b607250j

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title = "Direct observation of adsorbed H2-framework interactions in the Prussian Blue analogue MnII3[CoIII(CN) 6]2: The relative importance of accessible coordination sites and van der Waals interactions",

abstract = "Selective recovery of the guest-framework interactions for H2 adsorbed in a nanoporous Prussian Blue analogue, through differential X-ray and neutron pair distribution function analysis at ca. 77 K, suggests that the H2 molecule is disordered about a single position at the centre of the pore, (1/4,1/4,1/4), without binding at accessible MnII sites.",

author = "Chapman, \{Karena W.\} and Chupas, \{Peter J.\} and Maxey, \{Evan R.\} and Richardson, \{James W.\}",

year = "2006",

doi = "10.1039/b607250j",

language = "English",

pages = "4013--4015",

journal = "Chemical Communications",

issn = "1359-7345",

number = "38",

}

Direct observation of adsorbed H₂-framework interactions in the Prussian Blue analogue Mn^II₃[Co^III(CN) ₆]₂: The relative importance of accessible coordination sites and van der Waals interactions. / Chapman, Karena W.; Chupas, Peter J.; Maxey, Evan R. et al.
In: Chemical Communications, No. 38, 2006, p. 4013-4015.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Direct observation of adsorbed H2-framework interactions in the Prussian Blue analogue MnII3[CoIII(CN) 6]2

T2 - The relative importance of accessible coordination sites and van der Waals interactions

AU - Chapman, Karena W.

AU - Chupas, Peter J.

AU - Maxey, Evan R.

AU - Richardson, James W.

PY - 2006

Y1 - 2006

N2 - Selective recovery of the guest-framework interactions for H2 adsorbed in a nanoporous Prussian Blue analogue, through differential X-ray and neutron pair distribution function analysis at ca. 77 K, suggests that the H2 molecule is disordered about a single position at the centre of the pore, (1/4,1/4,1/4), without binding at accessible MnII sites.

AB - Selective recovery of the guest-framework interactions for H2 adsorbed in a nanoporous Prussian Blue analogue, through differential X-ray and neutron pair distribution function analysis at ca. 77 K, suggests that the H2 molecule is disordered about a single position at the centre of the pore, (1/4,1/4,1/4), without binding at accessible MnII sites.

UR - https://www.scopus.com/pages/publications/33749059839

U2 - 10.1039/b607250j

DO - 10.1039/b607250j

M3 - Article

AN - SCOPUS:33749059839

SN - 1359-7345

SP - 4013

EP - 4015

JO - Chemical Communications

JF - Chemical Communications

IS - 38

ER -

Direct observation of adsorbed H₂-framework interactions in the Prussian Blue analogue Mn^II₃[Co^III(CN) ₆]₂: The relative importance of accessible coordination sites and van der Waals interactions

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