Direct perfluoroalkylation of functionalized benzenes with perfluoroalkyl halides and copper bronze

Takamasa Fuchikami; Iwao Ojima

doi:10.1016/S0022-1139(00)81229-4

Direct perfluoroalkylation of functionalized benzenes with perfluoroalkyl halides and copper bronze

Takamasa Fuchikami
, Iwao Ojima

Chemistry

Sagami Chemical Research Institute

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

Perfluoroalkyl halides were found to react with functionalized benzenes in the presence of copper bronze to give the corresponding perfluoroalkylated products directly in moderate to good yields. The reaction may involve 'active species' other than perfluoroalkylcopper species. Synthetic utility and possible mechanisms of the present one-step reaction are discussed.

Original language	English
Pages (from-to)	541-556
Number of pages	16
Journal	Journal of Fluorine Chemistry
Volume	22
Issue number	6
DOIs	https://doi.org/10.1016/S0022-1139(00)81229-4
State	Published - Jun 1983

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10.1016/S0022-1139(00)81229-4

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@article{f27cba50e444456ea7450ae9a57f5fdc,

title = "Direct perfluoroalkylation of functionalized benzenes with perfluoroalkyl halides and copper bronze",

abstract = "Perfluoroalkyl halides were found to react with functionalized benzenes in the presence of copper bronze to give the corresponding perfluoroalkylated products directly in moderate to good yields. The reaction may involve 'active species' other than perfluoroalkylcopper species. Synthetic utility and possible mechanisms of the present one-step reaction are discussed.",

author = "Takamasa Fuchikami and Iwao Ojima",

year = "1983",

month = jun,

doi = "10.1016/S0022-1139(00)81229-4",

language = "English",

volume = "22",

pages = "541--556",

journal = "Journal of Fluorine Chemistry",

issn = "0022-1139",

number = "6",

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TY - JOUR

T1 - Direct perfluoroalkylation of functionalized benzenes with perfluoroalkyl halides and copper bronze

AU - Fuchikami, Takamasa

AU - Ojima, Iwao

PY - 1983/6

Y1 - 1983/6

N2 - Perfluoroalkyl halides were found to react with functionalized benzenes in the presence of copper bronze to give the corresponding perfluoroalkylated products directly in moderate to good yields. The reaction may involve 'active species' other than perfluoroalkylcopper species. Synthetic utility and possible mechanisms of the present one-step reaction are discussed.

AB - Perfluoroalkyl halides were found to react with functionalized benzenes in the presence of copper bronze to give the corresponding perfluoroalkylated products directly in moderate to good yields. The reaction may involve 'active species' other than perfluoroalkylcopper species. Synthetic utility and possible mechanisms of the present one-step reaction are discussed.

UR - https://www.scopus.com/pages/publications/0001348034

U2 - 10.1016/S0022-1139(00)81229-4

DO - 10.1016/S0022-1139(00)81229-4

M3 - Article

AN - SCOPUS:0001348034

SN - 0022-1139

VL - 22

SP - 541

EP - 556

JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

IS - 6

ER -

Direct perfluoroalkylation of functionalized benzenes with perfluoroalkyl halides and copper bronze

Abstract

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