Abstract
The present study demonstrates the development of a supramolecular porous ensemble consisting of hetero-oligophenylene derivative 6 and Au-Fe 3 O 4 nanodots. Supramolecular assemblies of AIE-active hetero-oligophenylene derivative 6 served as reactors for the generation of Au-Fe 3 O 4 nanodots. The as prepared supramolecular ensemble functioned as an efficient recyclable photocatalytic system for C(sp 2 )−H bond activation of anilines for the construction of quinoline carboxylates. Interestingly, the “dip catalyst” prepared by depositing PTh-co-PANI-6: Au-Fe 3 O 4 nanodots on a filter paper served as a recyclable strip (up to 10 cycles) for C−C/C−N bond formation reaction.
| Original language | English |
|---|---|
| Pages (from-to) | 809-813 |
| Number of pages | 5 |
| Journal | Chemistry - An Asian Journal |
| Volume | 14 |
| Issue number | 6 |
| DOIs | |
| State | Published - Mar 15 2019 |
Keywords
- aggregation-induced emission
- C−H activation
- oligophenylenes
- recyclable ′dip catalyst′
- supramolecular chemistry
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