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Encapsulating Au-Fe 3 O 4 Nanodots into AIE-active Supramolecular Assemblies: Ambient Visible-light Harvesting “Dip-Strip” Photocatalyst for C−C/C−N Bond Formation Reactions

  • Harpreet Kaur
  • , Mandeep Kaur
  • , Preet Kamal Walia
  • , Manoj Kumar
  • , Vandana Bhalla
  • Guru Nanak Dev University

Research output: Contribution to journalArticlepeer-review

16 Scopus citations

Abstract

The present study demonstrates the development of a supramolecular porous ensemble consisting of hetero-oligophenylene derivative 6 and Au-Fe 3 O 4 nanodots. Supramolecular assemblies of AIE-active hetero-oligophenylene derivative 6 served as reactors for the generation of Au-Fe 3 O 4 nanodots. The as prepared supramolecular ensemble functioned as an efficient recyclable photocatalytic system for C(sp 2 )−H bond activation of anilines for the construction of quinoline carboxylates. Interestingly, the “dip catalyst” prepared by depositing PTh-co-PANI-6: Au-Fe 3 O 4 nanodots on a filter paper served as a recyclable strip (up to 10 cycles) for C−C/C−N bond formation reaction.

Original languageEnglish
Pages (from-to)809-813
Number of pages5
JournalChemistry - An Asian Journal
Volume14
Issue number6
DOIs
StatePublished - Mar 15 2019

Keywords

  • aggregation-induced emission
  • C−H activation
  • oligophenylenes
  • recyclable ′dip catalyst′
  • supramolecular chemistry

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