Formation of Alkynyltrithiocarbonato Ligands from Alkylidyne Ligands and Carbon Disulfide

Andreas Mayr; Tsung‐Yi ‐Y Lee

doi:10.1002/anie.199317261

Formation of Alkynyltrithiocarbonato Ligands from Alkylidyne Ligands and Carbon Disulfide

Andreas Mayr
, Tsung‐Yi ‐Y Lee

Chemistry

Stony Brook University

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

An alkylidyne–thiocarbonyl coupling in intermediates in which a CS ligand has displaced a PMe₃ ligand is a plausible explanation for the formation of the tungsten complexes 2 in the reactions of alkylidyne complexes 1 with carbon disulfide. A carbonyl–alkylidyne coupling, which would also be reasonable, is not observed. X = halogen, RS. (Figure Presented.)

Original language	English
Pages (from-to)	1726-1727
Number of pages	2
Journal	Angewandte Chemie - International Edition
Volume	32
Issue number	12
DOIs	https://doi.org/10.1002/anie.199317261
State	Published - Dec 1993

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@article{a0ef69c70edb45e994024a399ed5f803,

title = "Formation of Alkynyltrithiocarbonato Ligands from Alkylidyne Ligands and Carbon Disulfide",

abstract = "An alkylidyne–thiocarbonyl coupling in intermediates in which a CS ligand has displaced a PMe3 ligand is a plausible explanation for the formation of the tungsten complexes 2 in the reactions of alkylidyne complexes 1 with carbon disulfide. A carbonyl–alkylidyne coupling, which would also be reasonable, is not observed. X = halogen, RS. (Figure Presented.)",

author = "Andreas Mayr and Lee, \{Tsung‐Yi ‐Y\}",

year = "1993",

month = dec,

doi = "10.1002/anie.199317261",

language = "English",

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pages = "1726--1727",

journal = "Angewandte Chemie - International Edition",

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T1 - Formation of Alkynyltrithiocarbonato Ligands from Alkylidyne Ligands and Carbon Disulfide

AU - Mayr, Andreas

AU - Lee, Tsung‐Yi ‐Y

PY - 1993/12

Y1 - 1993/12

N2 - An alkylidyne–thiocarbonyl coupling in intermediates in which a CS ligand has displaced a PMe3 ligand is a plausible explanation for the formation of the tungsten complexes 2 in the reactions of alkylidyne complexes 1 with carbon disulfide. A carbonyl–alkylidyne coupling, which would also be reasonable, is not observed. X = halogen, RS. (Figure Presented.)

AB - An alkylidyne–thiocarbonyl coupling in intermediates in which a CS ligand has displaced a PMe3 ligand is a plausible explanation for the formation of the tungsten complexes 2 in the reactions of alkylidyne complexes 1 with carbon disulfide. A carbonyl–alkylidyne coupling, which would also be reasonable, is not observed. X = halogen, RS. (Figure Presented.)

UR - https://www.scopus.com/pages/publications/33748245045

U2 - 10.1002/anie.199317261

DO - 10.1002/anie.199317261

M3 - Article

AN - SCOPUS:33748245045

SN - 1433-7851

VL - 32

SP - 1726

EP - 1727

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 12

ER -

Formation of Alkynyltrithiocarbonato Ligands from Alkylidyne Ligands and Carbon Disulfide

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