Functionalising metal-organic frameworks with metal complexes: the role of structural dynamics

Ana E. Platero-Prats; Antonio Bermejo Gómez; Karena W. Chapman; Belén Martín-Matute; Xiaodong Zou

doi:10.1039/c5ce01732g

Functionalising metal-organic frameworks with metal complexes: the role of structural dynamics

Ana E. Platero-Prats
, Antonio Bermejo Gómez
, Karena W. Chapman
, Belén Martín-Matute
, Xiaodong Zou

Chemistry

Berzelii Centre EXSELENT on Porous Materials
Stockholm University
United States Department of Energy

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

A series of iridium-functionalised UiO-67 metal-organic frameworks (MOFs) were synthesised under conditions that simulate kinetically- and thermodynamically-controlled regimes. The degree of functionalisation depends on the reaction time and relative acidity of the native- and metallo-linkers, and can be optimised by controlling the reaction time.

Original language	English
Pages (from-to)	7632-7635
Number of pages	4
Journal	CrystEngComm
Volume	17
Issue number	40
DOIs	https://doi.org/10.1039/c5ce01732g
State	Published - Sep 14 2015

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abstract = "A series of iridium-functionalised UiO-67 metal-organic frameworks (MOFs) were synthesised under conditions that simulate kinetically- and thermodynamically-controlled regimes. The degree of functionalisation depends on the reaction time and relative acidity of the native- and metallo-linkers, and can be optimised by controlling the reaction time.",

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T2 - the role of structural dynamics

AU - Platero-Prats, Ana E.

AU - Bermejo Gómez, Antonio

AU - Chapman, Karena W.

AU - Martín-Matute, Belén

AU - Zou, Xiaodong

PY - 2015/9/14

Y1 - 2015/9/14

N2 - A series of iridium-functionalised UiO-67 metal-organic frameworks (MOFs) were synthesised under conditions that simulate kinetically- and thermodynamically-controlled regimes. The degree of functionalisation depends on the reaction time and relative acidity of the native- and metallo-linkers, and can be optimised by controlling the reaction time.

AB - A series of iridium-functionalised UiO-67 metal-organic frameworks (MOFs) were synthesised under conditions that simulate kinetically- and thermodynamically-controlled regimes. The degree of functionalisation depends on the reaction time and relative acidity of the native- and metallo-linkers, and can be optimised by controlling the reaction time.

UR - https://www.scopus.com/pages/publications/84943791624

U2 - 10.1039/c5ce01732g

DO - 10.1039/c5ce01732g

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JF - CrystEngComm

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ER -

Functionalising metal-organic frameworks with metal complexes: the role of structural dynamics

Abstract

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