Halocarbon Chemistry. 1. (2-Hydroxyaryl)acetylenes from Haloethyl Aryl Ethers. A New O to C Rearrangement

Raghupathi Subramanian; Francis Johnson

doi:10.1021/jo00225a100

Halocarbon Chemistry. 1. (2-Hydroxyaryl)acetylenes from Haloethyl Aryl Ethers. A New O to C Rearrangement

Raghupathi Subramanian
, Francis Johnson

Pharmacological Sciences

Stony Brook University

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

A new base-induced (BuLi) oxygen-to-carbon rearrangement is described which involves the direct conversion of phenyl tetra(or tri)haloethyl ethers and the related intermediate phenoxyalkynes to the corresponding 1-(2-hydroxyphenyl)alkynes in good to excellent yield.

Original language	English
Pages (from-to)	5430-5432
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	50
Issue number	25
DOIs	https://doi.org/10.1021/jo00225a100
State	Published - Dec 1985

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@article{1fc22102b07d453784290616ce2c3e9f,

title = "Halocarbon Chemistry. 1. (2-Hydroxyaryl)acetylenes from Haloethyl Aryl Ethers. A New O to C Rearrangement",

abstract = "A new base-induced (BuLi) oxygen-to-carbon rearrangement is described which involves the direct conversion of phenyl tetra(or tri)haloethyl ethers and the related intermediate phenoxyalkynes to the corresponding 1-(2-hydroxyphenyl)alkynes in good to excellent yield.",

author = "Raghupathi Subramanian and Francis Johnson",

year = "1985",

month = dec,

doi = "10.1021/jo00225a100",

language = "English",

volume = "50",

pages = "5430--5432",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

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T1 - Halocarbon Chemistry. 1. (2-Hydroxyaryl)acetylenes from Haloethyl Aryl Ethers. A New O to C Rearrangement

AU - Subramanian, Raghupathi

AU - Johnson, Francis

PY - 1985/12

Y1 - 1985/12

N2 - A new base-induced (BuLi) oxygen-to-carbon rearrangement is described which involves the direct conversion of phenyl tetra(or tri)haloethyl ethers and the related intermediate phenoxyalkynes to the corresponding 1-(2-hydroxyphenyl)alkynes in good to excellent yield.

AB - A new base-induced (BuLi) oxygen-to-carbon rearrangement is described which involves the direct conversion of phenyl tetra(or tri)haloethyl ethers and the related intermediate phenoxyalkynes to the corresponding 1-(2-hydroxyphenyl)alkynes in good to excellent yield.

UR - https://www.scopus.com/pages/publications/0005821493

U2 - 10.1021/jo00225a100

DO - 10.1021/jo00225a100

M3 - Article

AN - SCOPUS:0005821493

SN - 0022-3263

VL - 50

SP - 5430

EP - 5432

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 25

ER -

Halocarbon Chemistry. 1. (2-Hydroxyaryl)acetylenes from Haloethyl Aryl Ethers. A New O to C Rearrangement

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