Kinetic analysis and solvent effects in the carbonylation of RuCl3·3H2O

Rina Tannenbaum

doi:10.1021/jp026187t

Kinetic analysis and solvent effects in the carbonylation of RuCl₃·3H₂O

Rina Tannenbaum

Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The carbonylation of RuCl₃·3H₂O in refluxing alcohol represents the entry point to ruthenium organometallic chemistry. The overall carbonylation reaction is composed of three consecutive reactions, each step resulting in a ruthenium carbonyl complex with different Ru/CO ratios. A kinetic analysis of the overall reaction reveals the parameters that are involved in the rates of formation of each compound, and as a result, provides a method for the control of product composition.

Original language	English
Pages (from-to)	9502-9505
Number of pages	4
Journal	Journal of Physical Chemistry A
Volume	106
Issue number	41
DOIs	https://doi.org/10.1021/jp026187t
State	Published - Oct 17 2002

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title = "Kinetic analysis and solvent effects in the carbonylation of RuCl3·3H2O",

abstract = "The carbonylation of RuCl3·3H2O in refluxing alcohol represents the entry point to ruthenium organometallic chemistry. The overall carbonylation reaction is composed of three consecutive reactions, each step resulting in a ruthenium carbonyl complex with different Ru/CO ratios. A kinetic analysis of the overall reaction reveals the parameters that are involved in the rates of formation of each compound, and as a result, provides a method for the control of product composition.",

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AB - The carbonylation of RuCl3·3H2O in refluxing alcohol represents the entry point to ruthenium organometallic chemistry. The overall carbonylation reaction is composed of three consecutive reactions, each step resulting in a ruthenium carbonyl complex with different Ru/CO ratios. A kinetic analysis of the overall reaction reveals the parameters that are involved in the rates of formation of each compound, and as a result, provides a method for the control of product composition.

UR - https://www.scopus.com/pages/publications/0037126117

U2 - 10.1021/jp026187t

DO - 10.1021/jp026187t

M3 - Article

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EP - 9505

JO - Journal of Physical Chemistry A

JF - Journal of Physical Chemistry A

IS - 41

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Kinetic analysis and solvent effects in the carbonylation of RuCl₃·3H₂O

Abstract

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