Linear free-energy relationship analysis of a catalytic desymmetrization reaction of a diarylmethane-bis(phenol)

Jeffrey L. Gustafson; Matthew S. Sigman; Scott J. Miller

doi:10.1021/ol100927m

Linear free-energy relationship analysis of a catalytic desymmetrization reaction of a diarylmethane-bis(phenol)

Jeffrey L. Gustafson
, Matthew S. Sigman
, Scott J. Miller

Chemistry

University of Utah
Yale University

Research output: Contribution to journal › Article › peer-review

58 Scopus citations

Abstract

(Figure presented) Linear free-energy relationships have been found for enantioselectivity and various steric parameters in an enantioselective desymmetrization of symmetrical bis(phenol) substrates. The potential origin of this observation and the role of different steric parameters are discussed.

Original language	English
Pages (from-to)	2794-2797
Number of pages	4
Journal	Organic Letters
Volume	12
Issue number	12
DOIs	https://doi.org/10.1021/ol100927m
State	Published - Jun 18 2010

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10.1021/ol100927m

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@article{83a8e54956a044209299793dbd0df20c,

title = "Linear free-energy relationship analysis of a catalytic desymmetrization reaction of a diarylmethane-bis(phenol)",

abstract = "(Figure presented) Linear free-energy relationships have been found for enantioselectivity and various steric parameters in an enantioselective desymmetrization of symmetrical bis(phenol) substrates. The potential origin of this observation and the role of different steric parameters are discussed.",

author = "Gustafson, \{Jeffrey L.\} and Sigman, \{Matthew S.\} and Miller, \{Scott J.\}",

year = "2010",

month = jun,

day = "18",

doi = "10.1021/ol100927m",

language = "English",

volume = "12",

pages = "2794--2797",

journal = "Organic Letters",

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T1 - Linear free-energy relationship analysis of a catalytic desymmetrization reaction of a diarylmethane-bis(phenol)

AU - Gustafson, Jeffrey L.

AU - Sigman, Matthew S.

AU - Miller, Scott J.

PY - 2010/6/18

Y1 - 2010/6/18

N2 - (Figure presented) Linear free-energy relationships have been found for enantioselectivity and various steric parameters in an enantioselective desymmetrization of symmetrical bis(phenol) substrates. The potential origin of this observation and the role of different steric parameters are discussed.

AB - (Figure presented) Linear free-energy relationships have been found for enantioselectivity and various steric parameters in an enantioselective desymmetrization of symmetrical bis(phenol) substrates. The potential origin of this observation and the role of different steric parameters are discussed.

UR - https://www.scopus.com/pages/publications/77953581294

U2 - 10.1021/ol100927m

DO - 10.1021/ol100927m

M3 - Article

C2 - 20486656

AN - SCOPUS:77953581294

SN - 1523-7060

VL - 12

SP - 2794

EP - 2797

JO - Organic Letters

JF - Organic Letters

IS - 12

ER -

Linear free-energy relationship analysis of a catalytic desymmetrization reaction of a diarylmethane-bis(phenol)

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