Lithium based metal-organic framework with exceptional stability

Debasis Banerjee; Sun Jin Kim; John B. Parise

doi:10.1021/cg8014157

Lithium based metal-organic framework with exceptional stability

Debasis Banerjee
, Sun Jin Kim
, John B. Parise

Geosciences

Stony Brook University
Korea Institute of Science and Technology

Research output: Contribution to journal › Article › peer-review

95 Scopus citations

Abstract

A three-dimensional lithium based metal-organic framework Li ₂(2,6-NDC) (1); UL-MOF-1, UL = ultralight; NDC = napthalenedicarboxylate; space group P2 ₁/c, a = 10.302(5), b = 5.345(2), c = 8.663(4) Å, β ) 98.659(9)°, V = 471.6(4) Å ³ was synthesized. The framework is stable to 610 °C. The synthesis of 1 was achieved using solvothermal methods in N,Ndimethylformamide at 180 °C and was characterized by single crystal X-ray diffraction. The structure consists of layers of twodimensional antifluorite related LiO connected by the NDC linker.

Original language	English
Pages (from-to)	2500-2503
Number of pages	4
Journal	Crystal Growth and Design
Volume	9
Issue number	5
DOIs	https://doi.org/10.1021/cg8014157
State	Published - May 6 2009

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title = "Lithium based metal-organic framework with exceptional stability",

abstract = "A three-dimensional lithium based metal-organic framework Li 2(2,6-NDC) (1); UL-MOF-1, UL = ultralight; NDC = napthalenedicarboxylate; space group P2 1/c, a = 10.302(5), b = 5.345(2), c = 8.663(4) {\AA}, β ) 98.659(9)°, V = 471.6(4) {\AA} 3 was synthesized. The framework is stable to 610 °C. The synthesis of 1 was achieved using solvothermal methods in N,Ndimethylformamide at 180 °C and was characterized by single crystal X-ray diffraction. The structure consists of layers of twodimensional antifluorite related LiO connected by the NDC linker.",

author = "Debasis Banerjee and Kim, \{Sun Jin\} and Parise, \{John B.\}",

year = "2009",

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doi = "10.1021/cg8014157",

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journal = "Crystal Growth and Design",

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T1 - Lithium based metal-organic framework with exceptional stability

AU - Banerjee, Debasis

AU - Kim, Sun Jin

AU - Parise, John B.

PY - 2009/5/6

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N2 - A three-dimensional lithium based metal-organic framework Li 2(2,6-NDC) (1); UL-MOF-1, UL = ultralight; NDC = napthalenedicarboxylate; space group P2 1/c, a = 10.302(5), b = 5.345(2), c = 8.663(4) Å, β ) 98.659(9)°, V = 471.6(4) Å 3 was synthesized. The framework is stable to 610 °C. The synthesis of 1 was achieved using solvothermal methods in N,Ndimethylformamide at 180 °C and was characterized by single crystal X-ray diffraction. The structure consists of layers of twodimensional antifluorite related LiO connected by the NDC linker.

AB - A three-dimensional lithium based metal-organic framework Li 2(2,6-NDC) (1); UL-MOF-1, UL = ultralight; NDC = napthalenedicarboxylate; space group P2 1/c, a = 10.302(5), b = 5.345(2), c = 8.663(4) Å, β ) 98.659(9)°, V = 471.6(4) Å 3 was synthesized. The framework is stable to 610 °C. The synthesis of 1 was achieved using solvothermal methods in N,Ndimethylformamide at 180 °C and was characterized by single crystal X-ray diffraction. The structure consists of layers of twodimensional antifluorite related LiO connected by the NDC linker.

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DO - 10.1021/cg8014157

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SP - 2500

EP - 2503

JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 5

ER -

Lithium based metal-organic framework with exceptional stability

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