Lonothermal synthesis and magnetic studies of novel two-dimensional metal - Formate frameworks

Paul J. Calderone; Paul M. Forster; Lauren A. Borkowski; Simon J. Teat; Mikhail Feygenson; Meigan C. Aronson; John B. Parise

doi:10.1021/ic1015548

Lonothermal synthesis and magnetic studies of novel two-dimensional metal - Formate frameworks

Paul J. Calderone
, Paul M. Forster
, Lauren A. Borkowski
, Simon J. Teat
, Mikhail Feygenson
, Meigan C. Aronson
, John B. Parise

Geosciences

Stony Brook University
University of Nevada, Las Vegas
Lawrence Berkeley National Laboratory
Brookhaven National Laboratory Condensed Matter Physics and Materials Science Department

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

Five novel two-dimensional frameworks containing formatebridged metal-centered octahedra are synthesized ionothermally from two ionic liquids previously unused as solvents in hybrid synthesis, 2-hydroxyethylammonium (HEA) formate, and 1-hydroxy-3-proplyammonium (HPA formate. Templating effects of the cation from each ionic liquid drive the formation of different structures. [NH₃C₂H₄OH]₂[M(CHO₂) ₄](l:M = Co, 2: M = Ni) exhibit the same stoichiometry and connectivity as their manganese analogue (3: M = Mn), but the manganese form exhibits a different topology from 1 and 2.[NH₃C₃H ₆OH][M(CHO₂)₃(H₂O)] (4:M = Co, 5:M = Mn) were synthesized using the HPA formate ionic liquid with a metal-formate connectivity related to those of 1-3. Canted antiferromagnetic ordering occurs at low temperatures (1: T_N = 7.0 K, 2: T_N = 4.6 K, 3: T_N = 8.0 K, 4: T_N = 7.0 K, 5: T_N = 9.2 K), similar to the magnetic properties previously reported for other metal-formate hybrid materials.

Original language	English
Pages (from-to)	2159-2167
Number of pages	9
Journal	Inorganic Chemistry
Volume	50
Issue number	6
DOIs	https://doi.org/10.1021/ic1015548
State	Published - Mar 21 2011

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@article{206324df04bd48a09266d5730d344e8a,

title = "Lonothermal synthesis and magnetic studies of novel two-dimensional metal - Formate frameworks",

abstract = "Five novel two-dimensional frameworks containing formatebridged metal-centered octahedra are synthesized ionothermally from two ionic liquids previously unused as solvents in hybrid synthesis, 2-hydroxyethylammonium (HEA) formate, and 1-hydroxy-3-proplyammonium (HPA formate. Templating effects of the cation from each ionic liquid drive the formation of different structures. [NH3C2H4OH]2[M(CHO2) 4](l:M = Co, 2: M = Ni) exhibit the same stoichiometry and connectivity as their manganese analogue (3: M = Mn), but the manganese form exhibits a different topology from 1 and 2.[NH3C3H 6OH][M(CHO2)3(H2O)] (4:M = Co, 5:M = Mn) were synthesized using the HPA formate ionic liquid with a metal-formate connectivity related to those of 1-3. Canted antiferromagnetic ordering occurs at low temperatures (1: TN = 7.0 K, 2: TN = 4.6 K, 3: TN = 8.0 K, 4: TN = 7.0 K, 5: TN = 9.2 K), similar to the magnetic properties previously reported for other metal-formate hybrid materials.",

author = "Calderone, \{Paul J.\} and Forster, \{Paul M.\} and Borkowski, \{Lauren A.\} and Teat, \{Simon J.\} and Mikhail Feygenson and Aronson, \{Meigan C.\} and Parise, \{John B.\}",

year = "2011",

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doi = "10.1021/ic1015548",

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journal = "Inorganic Chemistry",

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T1 - Lonothermal synthesis and magnetic studies of novel two-dimensional metal - Formate frameworks

AU - Calderone, Paul J.

AU - Forster, Paul M.

AU - Borkowski, Lauren A.

AU - Teat, Simon J.

AU - Feygenson, Mikhail

AU - Aronson, Meigan C.

AU - Parise, John B.

PY - 2011/3/21

Y1 - 2011/3/21

N2 - Five novel two-dimensional frameworks containing formatebridged metal-centered octahedra are synthesized ionothermally from two ionic liquids previously unused as solvents in hybrid synthesis, 2-hydroxyethylammonium (HEA) formate, and 1-hydroxy-3-proplyammonium (HPA formate. Templating effects of the cation from each ionic liquid drive the formation of different structures. [NH3C2H4OH]2[M(CHO2) 4](l:M = Co, 2: M = Ni) exhibit the same stoichiometry and connectivity as their manganese analogue (3: M = Mn), but the manganese form exhibits a different topology from 1 and 2.[NH3C3H 6OH][M(CHO2)3(H2O)] (4:M = Co, 5:M = Mn) were synthesized using the HPA formate ionic liquid with a metal-formate connectivity related to those of 1-3. Canted antiferromagnetic ordering occurs at low temperatures (1: TN = 7.0 K, 2: TN = 4.6 K, 3: TN = 8.0 K, 4: TN = 7.0 K, 5: TN = 9.2 K), similar to the magnetic properties previously reported for other metal-formate hybrid materials.

AB - Five novel two-dimensional frameworks containing formatebridged metal-centered octahedra are synthesized ionothermally from two ionic liquids previously unused as solvents in hybrid synthesis, 2-hydroxyethylammonium (HEA) formate, and 1-hydroxy-3-proplyammonium (HPA formate. Templating effects of the cation from each ionic liquid drive the formation of different structures. [NH3C2H4OH]2[M(CHO2) 4](l:M = Co, 2: M = Ni) exhibit the same stoichiometry and connectivity as their manganese analogue (3: M = Mn), but the manganese form exhibits a different topology from 1 and 2.[NH3C3H 6OH][M(CHO2)3(H2O)] (4:M = Co, 5:M = Mn) were synthesized using the HPA formate ionic liquid with a metal-formate connectivity related to those of 1-3. Canted antiferromagnetic ordering occurs at low temperatures (1: TN = 7.0 K, 2: TN = 4.6 K, 3: TN = 8.0 K, 4: TN = 7.0 K, 5: TN = 9.2 K), similar to the magnetic properties previously reported for other metal-formate hybrid materials.

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U2 - 10.1021/ic1015548

DO - 10.1021/ic1015548

M3 - Article

AN - SCOPUS:79954433181

SN - 0020-1669

VL - 50

SP - 2159

EP - 2167

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 6

ER -

Lonothermal synthesis and magnetic studies of novel two-dimensional metal - Formate frameworks

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