Modeling zeolites with metal-supported two-dimensional aluminosilicate films

Jorge Anibal Boscoboinik; Xin Yu; Bing Yang; Frank Daniel Fischer; Radosaw Wodarczyk; Marek Sierka; Shamil Shaikhutdinov; Joachim Sauer; Hans Joachim Freund

doi:10.1002/anie.201201319

Modeling zeolites with metal-supported two-dimensional aluminosilicate films

Jorge Anibal Boscoboinik
, Xin Yu
, Bing Yang
, Frank Daniel Fischer
, Radosaw Wodarczyk
, Marek Sierka
, Shamil Shaikhutdinov
, Joachim Sauer
, Hans Joachim Freund

Materials Science and Engineering

Fritz Haber Institute of the Max Planck Society
Humboldt University of Berlin
Friedrich Schiller University Jena

Research output: Contribution to journal › Article › peer-review

105 Scopus citations

Abstract

Flat pore models: Thin, well-defined aluminosilicate films with tetrahedral [SiO _4/2] and [AlO _4/2 ^-] building blocks that are weakly bound to an underlying metal support contain highly acidic bridging OH species, which exhibit H-D exchange (see picture; Siyellow, Ored, Algray, Cblack, Hwhite). These films are a model system for surface-science studies of the inner walls of zeolite pores.

Original language	English
Pages (from-to)	6005-6008
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	24
DOIs	https://doi.org/10.1002/anie.201201319
State	Published - Jun 11 2012

Keywords

IR spectroscopy
density functional calculations
surface structures
thin films
zeolites

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10.1002/anie.201201319

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title = "Modeling zeolites with metal-supported two-dimensional aluminosilicate films",

abstract = "Flat pore models: Thin, well-defined aluminosilicate films with tetrahedral [SiO 4/2] and [AlO 4/2 -] building blocks that are weakly bound to an underlying metal support contain highly acidic bridging OH species, which exhibit H-D exchange (see picture; Siyellow, Ored, Algray, Cblack, Hwhite). These films are a model system for surface-science studies of the inner walls of zeolite pores.",

keywords = "IR spectroscopy, density functional calculations, surface structures, thin films, zeolites",

author = "Boscoboinik, \{Jorge Anibal\} and Xin Yu and Bing Yang and Fischer, \{Frank Daniel\} and Radosaw Wodarczyk and Marek Sierka and Shamil Shaikhutdinov and Joachim Sauer and Freund, \{Hans Joachim\}",

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AU - Boscoboinik, Jorge Anibal

AU - Yu, Xin

AU - Yang, Bing

AU - Fischer, Frank Daniel

AU - Wodarczyk, Radosaw

AU - Sierka, Marek

AU - Shaikhutdinov, Shamil

AU - Sauer, Joachim

AU - Freund, Hans Joachim

PY - 2012/6/11

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N2 - Flat pore models: Thin, well-defined aluminosilicate films with tetrahedral [SiO 4/2] and [AlO 4/2 -] building blocks that are weakly bound to an underlying metal support contain highly acidic bridging OH species, which exhibit H-D exchange (see picture; Siyellow, Ored, Algray, Cblack, Hwhite). These films are a model system for surface-science studies of the inner walls of zeolite pores.

AB - Flat pore models: Thin, well-defined aluminosilicate films with tetrahedral [SiO 4/2] and [AlO 4/2 -] building blocks that are weakly bound to an underlying metal support contain highly acidic bridging OH species, which exhibit H-D exchange (see picture; Siyellow, Ored, Algray, Cblack, Hwhite). These films are a model system for surface-science studies of the inner walls of zeolite pores.

KW - IR spectroscopy

KW - density functional calculations

KW - surface structures

KW - thin films

KW - zeolites

UR - https://www.scopus.com/pages/publications/84861880837

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DO - 10.1002/anie.201201319

M3 - Article

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 24

ER -

Modeling zeolites with metal-supported two-dimensional aluminosilicate films

Abstract

Keywords

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