Modulating conductivity in materials by design: Battery relevant study of Ag+ on the exposed surface of Agu3Mn8Oi6 nanowires

Bingjie Zhang; Julia Reilly; Esther S. Takeuchi; Kenneth J. Takeuchi; Amy C. Marschilok

doi:10.1149/07711.0305ecst

Modulating conductivity in materials by design: Battery relevant study of Ag⁺ on the exposed surface of Agu₃Mn₈Oi₆ nanowires

Bingjie Zhang
, Julia Reilly
, Esther S. Takeuchi
, Kenneth J. Takeuchi
, Amy C. Marschilok

Stony Brook University
Le Moyne College

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

Design and development of novel materials can have a profound impact on the electrochemical properties of energy storage systems. Silver ion when electrochemically reduced to generate conductive silver metal in-situ can provide enhanced conductivity in electrochemical energy storage systems. In this research, Ag₂O surface modified silver hollandite (Ag_xMn₈O₁₆, α-MnO₂ structure) has been successfully synthesized and its physical, chemical, and electrochemical properties have been studied. The electrochemical tests indicate a higher functional capacity can be delivered with higher Ag₂O loading, consistent with an increase in the electric conductivity of the material. This result demonstrates the ability to modulate conductivity in materials by design.

Original language	English
Title of host publication	Selected Proceedings from the 231st ECS Meeting New Orleans, LA - Spring 2017
Publisher	Electrochemical Society Inc.
Pages	305-310
Number of pages	6
Edition	11
ISBN (Electronic)	9781607688174
ISBN (Print)	9781623324605
DOIs	https://doi.org/10.1149/07711.0305ecst
State	Published - 2017
Event	231st ECS Meeting - New Orleans, United States Duration: May 28 2017 → Jun 1 2017

Publication series

Name	ECS Transactions
Number	11
Volume	77
ISSN (Print)	1938-6737
ISSN (Electronic)	1938-5862

Conference

Conference	231st ECS Meeting
Country/Territory	United States
City	New Orleans
Period	05/28/17 → 06/1/17

Access to Document

10.1149/07711.0305ecst

Cite this

Zhang, B., Reilly, J., Takeuchi, E. S., Takeuchi, K. J., & Marschilok, A. C. (2017). Modulating conductivity in materials by design: Battery relevant study of Ag⁺ on the exposed surface of Agu₃Mn₈Oi₆ nanowires. In Selected Proceedings from the 231st ECS Meeting New Orleans, LA - Spring 2017 (11 ed., pp. 305-310). (ECS Transactions; Vol. 77, No. 11). Electrochemical Society Inc.. https://doi.org/10.1149/07711.0305ecst

@inproceedings{20672da7d32b4d60b160a754dddc13df,

title = "Modulating conductivity in materials by design: Battery relevant study of Ag+ on the exposed surface of Agu3Mn8Oi6 nanowires",

abstract = "Design and development of novel materials can have a profound impact on the electrochemical properties of energy storage systems. Silver ion when electrochemically reduced to generate conductive silver metal in-situ can provide enhanced conductivity in electrochemical energy storage systems. In this research, Ag2O surface modified silver hollandite (AgxMn8O16, α-MnO2 structure) has been successfully synthesized and its physical, chemical, and electrochemical properties have been studied. The electrochemical tests indicate a higher functional capacity can be delivered with higher Ag2O loading, consistent with an increase in the electric conductivity of the material. This result demonstrates the ability to modulate conductivity in materials by design.",

author = "Bingjie Zhang and Julia Reilly and Takeuchi, \{Esther S.\} and Takeuchi, \{Kenneth J.\} and Marschilok, \{Amy C.\}",

note = "Publisher Copyright: {\textcopyright} 2017 The Electrochemical Society.; 231st ECS Meeting ; Conference date: 28-05-2017 Through 01-06-2017",

year = "2017",

doi = "10.1149/07711.0305ecst",

language = "English",

isbn = "9781623324605",

series = "ECS Transactions",

publisher = "Electrochemical Society Inc.",

number = "11",

pages = "305--310",

booktitle = "Selected Proceedings from the 231st ECS Meeting New Orleans, LA - Spring 2017",

edition = "11",

}

Zhang, B, Reilly, J, Takeuchi, ES , Takeuchi, KJ & Marschilok, AC 2017, Modulating conductivity in materials by design: Battery relevant study of Ag⁺ on the exposed surface of Agu₃Mn₈Oi₆ nanowires. in Selected Proceedings from the 231st ECS Meeting New Orleans, LA - Spring 2017. 11 edn, ECS Transactions, no. 11, vol. 77, Electrochemical Society Inc., pp. 305-310, 231st ECS Meeting, New Orleans, United States, 05/28/17. https://doi.org/10.1149/07711.0305ecst

Modulating conductivity in materials by design: Battery relevant study of Ag⁺ on the exposed surface of Agu₃Mn₈Oi₆ nanowires. / Zhang, Bingjie; Reilly, Julia; Takeuchi, Esther S. et al.
Selected Proceedings from the 231st ECS Meeting New Orleans, LA - Spring 2017. 11. ed. Electrochemical Society Inc., 2017. p. 305-310 (ECS Transactions; Vol. 77, No. 11).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Modulating conductivity in materials by design

T2 - 231st ECS Meeting

AU - Zhang, Bingjie

AU - Reilly, Julia

AU - Takeuchi, Esther S.

AU - Takeuchi, Kenneth J.

AU - Marschilok, Amy C.

PY - 2017

Y1 - 2017

N2 - Design and development of novel materials can have a profound impact on the electrochemical properties of energy storage systems. Silver ion when electrochemically reduced to generate conductive silver metal in-situ can provide enhanced conductivity in electrochemical energy storage systems. In this research, Ag2O surface modified silver hollandite (AgxMn8O16, α-MnO2 structure) has been successfully synthesized and its physical, chemical, and electrochemical properties have been studied. The electrochemical tests indicate a higher functional capacity can be delivered with higher Ag2O loading, consistent with an increase in the electric conductivity of the material. This result demonstrates the ability to modulate conductivity in materials by design.

AB - Design and development of novel materials can have a profound impact on the electrochemical properties of energy storage systems. Silver ion when electrochemically reduced to generate conductive silver metal in-situ can provide enhanced conductivity in electrochemical energy storage systems. In this research, Ag2O surface modified silver hollandite (AgxMn8O16, α-MnO2 structure) has been successfully synthesized and its physical, chemical, and electrochemical properties have been studied. The electrochemical tests indicate a higher functional capacity can be delivered with higher Ag2O loading, consistent with an increase in the electric conductivity of the material. This result demonstrates the ability to modulate conductivity in materials by design.

UR - https://www.scopus.com/pages/publications/85030453212

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DO - 10.1149/07711.0305ecst

M3 - Conference contribution

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BT - Selected Proceedings from the 231st ECS Meeting New Orleans, LA - Spring 2017

PB - Electrochemical Society Inc.

Y2 - 28 May 2017 through 1 June 2017

ER -

Zhang B, Reilly J, Takeuchi ES , Takeuchi KJ , Marschilok AC. Modulating conductivity in materials by design: Battery relevant study of Ag⁺ on the exposed surface of Agu₃Mn₈Oi₆ nanowires. In Selected Proceedings from the 231st ECS Meeting New Orleans, LA - Spring 2017. 11 ed. Electrochemical Society Inc. 2017. p. 305-310. (ECS Transactions; 11). doi: 10.1149/07711.0305ecst