Molecular dynamics and microstructure development during cold crystallization in poly(ether-ether-ketone) as revealed by real time dielectric and x-ray methods

A. Nogales; T. A. Ezquerra; Z. Denchev; I. Šics; F. J. Baltá Calleja; Benjamin S. Hsiao

doi:10.1063/1.1388627

Molecular dynamics and microstructure development during cold crystallization in poly(ether-ether-ketone) as revealed by real time dielectric and x-ray methods

A. Nogales
, T. A. Ezquerra
, Z. Denchev
, I. Šics
, F. J. Baltá Calleja
, Benjamin S. Hsiao

Chemistry

CSIC - Instituto de Estructura de la Materia (IEM)

Research output: Contribution to journal › Article › peer-review

61 Scopus citations

Abstract

An in-depth and complete picture of crystallization processes from the glass in poly(ether-ether-ketone) (PEEK) was established using a combination of real time techniques revealing the parallel evolution of the crystalline phase (WAXS and SAXS) together with methods detecting the real time changes in the amorphous phase (dielectric spectroscopy). The obtained results support the concept that sample morphology consists of lamellar stacks, separated by broad amorphous regions.

Original language	English
Pages (from-to)	3804-3813
Number of pages	10
Journal	Journal of Chemical Physics
Volume	115
Issue number	8
DOIs	https://doi.org/10.1063/1.1388627
State	Published - Aug 22 2001

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title = "Molecular dynamics and microstructure development during cold crystallization in poly(ether-ether-ketone) as revealed by real time dielectric and x-ray methods",

abstract = "An in-depth and complete picture of crystallization processes from the glass in poly(ether-ether-ketone) (PEEK) was established using a combination of real time techniques revealing the parallel evolution of the crystalline phase (WAXS and SAXS) together with methods detecting the real time changes in the amorphous phase (dielectric spectroscopy). The obtained results support the concept that sample morphology consists of lamellar stacks, separated by broad amorphous regions.",

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AU - Nogales, A.

AU - Ezquerra, T. A.

AU - Denchev, Z.

AU - Šics, I.

AU - Baltá Calleja, F. J.

AU - Hsiao, Benjamin S.

PY - 2001/8/22

Y1 - 2001/8/22

N2 - An in-depth and complete picture of crystallization processes from the glass in poly(ether-ether-ketone) (PEEK) was established using a combination of real time techniques revealing the parallel evolution of the crystalline phase (WAXS and SAXS) together with methods detecting the real time changes in the amorphous phase (dielectric spectroscopy). The obtained results support the concept that sample morphology consists of lamellar stacks, separated by broad amorphous regions.

AB - An in-depth and complete picture of crystallization processes from the glass in poly(ether-ether-ketone) (PEEK) was established using a combination of real time techniques revealing the parallel evolution of the crystalline phase (WAXS and SAXS) together with methods detecting the real time changes in the amorphous phase (dielectric spectroscopy). The obtained results support the concept that sample morphology consists of lamellar stacks, separated by broad amorphous regions.

UR - https://www.scopus.com/pages/publications/0035934249

U2 - 10.1063/1.1388627

DO - 10.1063/1.1388627

M3 - Article

AN - SCOPUS:0035934249

SN - 0021-9606

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JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 8

ER -

Molecular dynamics and microstructure development during cold crystallization in poly(ether-ether-ketone) as revealed by real time dielectric and x-ray methods

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