Negative thermal expansion in the metal-organic framework material Cu 3(1,3,5-benzenetricarboxylate)2

Yue Wu; Atsushi Kobayashi; Gregory J. Halder; Vanessa K. Peterson; Karena W. Chapman; Nina Lock; Peter D. Southon; Cameron J. Kepert

doi:10.1002/anie.200803925

Negative thermal expansion in the metal-organic framework material Cu ₃(1,3,5-benzenetricarboxylate)₂

Yue Wu
, Atsushi Kobayashi
, Gregory J. Halder
, Vanessa K. Peterson
, Karena W. Chapman
, Nina Lock
, Peter D. Southon
, Cameron J. Kepert

Chemistry

The University of Sydney
Hokkaido University
Argonne National Laboratory
Australian Nuclear Science and Technology Organisation
Aarhus University

Research output: Contribution to journal › Article › peer-review

280 Scopus citations

Abstract

The action behind contraction: The metal-organic framework [Cu ₃(btc)₂] displays negative thermal expansion (NTE) over a broad temperature range. This property arises from two coincident mechanisms, each of which are unique for NTE systems: the concerted transverse vibration of triangular organic linkers, and the local dynamic distortion of dinuclear metal centers within the framework lattice. (Graph Presented).

Original language	English
Pages (from-to)	8929-8932
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	46
DOIs	https://doi.org/10.1002/anie.200803925
State	Published - Nov 3 2008

Keywords

Coordination frameworks
Materials science
Metal-organic frameworks
Microporous materials
Thermal expansion

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10.1002/anie.200803925

Cite this

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title = "Negative thermal expansion in the metal-organic framework material Cu 3(1,3,5-benzenetricarboxylate)2",

abstract = "The action behind contraction: The metal-organic framework [Cu 3(btc)2] displays negative thermal expansion (NTE) over a broad temperature range. This property arises from two coincident mechanisms, each of which are unique for NTE systems: the concerted transverse vibration of triangular organic linkers, and the local dynamic distortion of dinuclear metal centers within the framework lattice. (Graph Presented).",

keywords = "Coordination frameworks, Materials science, Metal-organic frameworks, Microporous materials, Thermal expansion",

author = "Yue Wu and Atsushi Kobayashi and Halder, \{Gregory J.\} and Peterson, \{Vanessa K.\} and Chapman, \{Karena W.\} and Nina Lock and Southon, \{Peter D.\} and Kepert, \{Cameron J.\}",

year = "2008",

month = nov,

day = "3",

doi = "10.1002/anie.200803925",

language = "English",

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pages = "8929--8932",

journal = "Angewandte Chemie - International Edition",

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T1 - Negative thermal expansion in the metal-organic framework material Cu 3(1,3,5-benzenetricarboxylate)2

AU - Wu, Yue

AU - Kobayashi, Atsushi

AU - Halder, Gregory J.

AU - Peterson, Vanessa K.

AU - Chapman, Karena W.

AU - Lock, Nina

AU - Southon, Peter D.

AU - Kepert, Cameron J.

PY - 2008/11/3

Y1 - 2008/11/3

N2 - The action behind contraction: The metal-organic framework [Cu 3(btc)2] displays negative thermal expansion (NTE) over a broad temperature range. This property arises from two coincident mechanisms, each of which are unique for NTE systems: the concerted transverse vibration of triangular organic linkers, and the local dynamic distortion of dinuclear metal centers within the framework lattice. (Graph Presented).

AB - The action behind contraction: The metal-organic framework [Cu 3(btc)2] displays negative thermal expansion (NTE) over a broad temperature range. This property arises from two coincident mechanisms, each of which are unique for NTE systems: the concerted transverse vibration of triangular organic linkers, and the local dynamic distortion of dinuclear metal centers within the framework lattice. (Graph Presented).

KW - Coordination frameworks

KW - Materials science

KW - Metal-organic frameworks

KW - Microporous materials

KW - Thermal expansion

UR - https://www.scopus.com/pages/publications/57349199486

U2 - 10.1002/anie.200803925

DO - 10.1002/anie.200803925

M3 - Article

AN - SCOPUS:57349199486

SN - 1433-7851

VL - 47

SP - 8929

EP - 8932

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 46

ER -

Negative thermal expansion in the metal-organic framework material Cu ₃(1,3,5-benzenetricarboxylate)₂

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Keywords

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