New cascade silylcarbocyclization (SiCaC) of enediynes

Iwao Ojima; James V. McCullagh; William R. Shay

doi:10.1016/0022-328X(96)06359-0

New cascade silylcarbocyclization (SiCaC) of enediynes

Iwao Ojima
, James V. McCullagh
, William R. Shay

Chemistry

Stony Brook University

Research output: Contribution to journal › Article › peer-review

32 Scopus citations

Abstract

The Rh(acac)(CO)₂-catalyzed cascade silylcarbocyclizations (SiCaC) of (6E)-and (6Z)-dodec-6-ene-1,11-diynes stereospecifically give (R*,R*)-and (S*,R*)-bis(exo-methylenecyclopentyl) respectively in good isolated yields.

Original language	English
Pages (from-to)	421-423
Number of pages	3
Journal	Journal of Organometallic Chemistry
Volume	521
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(96)06359-0
State	Published - Aug 23 1996

Keywords

Bis(exo-methylenecyclopentyl)
Catalysis
Endiynes
Rhodium
Silicon
Silylcarbocyclization

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10.1016/0022-328X(96)06359-0

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title = "New cascade silylcarbocyclization (SiCaC) of enediynes",

abstract = "The Rh(acac)(CO)2-catalyzed cascade silylcarbocyclizations (SiCaC) of (6E)-and (6Z)-dodec-6-ene-1,11-diynes stereospecifically give (R*,R*)-and (S*,R*)-bis(exo-methylenecyclopentyl) respectively in good isolated yields.",

keywords = "Bis(exo-methylenecyclopentyl), Catalysis, Endiynes, Rhodium, Silicon, Silylcarbocyclization",

author = "Iwao Ojima and McCullagh, \{James V.\} and Shay, \{William R.\}",

year = "1996",

month = aug,

day = "23",

doi = "10.1016/0022-328X(96)06359-0",

language = "English",

volume = "521",

pages = "421--423",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

number = "1-2",

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TY - JOUR

T1 - New cascade silylcarbocyclization (SiCaC) of enediynes

AU - Ojima, Iwao

AU - McCullagh, James V.

AU - Shay, William R.

PY - 1996/8/23

Y1 - 1996/8/23

N2 - The Rh(acac)(CO)2-catalyzed cascade silylcarbocyclizations (SiCaC) of (6E)-and (6Z)-dodec-6-ene-1,11-diynes stereospecifically give (R*,R*)-and (S*,R*)-bis(exo-methylenecyclopentyl) respectively in good isolated yields.

AB - The Rh(acac)(CO)2-catalyzed cascade silylcarbocyclizations (SiCaC) of (6E)-and (6Z)-dodec-6-ene-1,11-diynes stereospecifically give (R*,R*)-and (S*,R*)-bis(exo-methylenecyclopentyl) respectively in good isolated yields.

KW - Bis(exo-methylenecyclopentyl)

KW - Catalysis

KW - Endiynes

KW - Rhodium

KW - Silicon

KW - Silylcarbocyclization

UR - https://www.scopus.com/pages/publications/0030598772

U2 - 10.1016/0022-328X(96)06359-0

DO - 10.1016/0022-328X(96)06359-0

M3 - Article

AN - SCOPUS:0030598772

SN - 0022-328X

VL - 521

SP - 421

EP - 423

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

New cascade silylcarbocyclization (SiCaC) of enediynes

Abstract

Keywords

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