Novel biobased resins from blends of functionalized soybean oil and unsaturated polyester resin

Hiroaki Miyagawa; Amar K. Mohanty; Rigoberto Burgueño; Lawrence T. Drzal; Manjusri Misra

doi:10.1002/polb.21059

Novel biobased resins from blends of functionalized soybean oil and unsaturated polyester resin

Hiroaki Miyagawa
, Amar K. Mohanty
, Rigoberto Burgueño
, Lawrence T. Drzal
, Manjusri Misra

Civil Engineering

Michigan State University
Nitto Denko Corporation

Research output: Contribution to journal › Article › peer-review

78 Scopus citations

Abstract

Biobased unsaturated polyester (UPE) materials containing epoxidized methyl soyate (EMS) were processed with cobalt naphthenate as a promoter and 2-butanone peroxide as an initiator. A certain amount of the UPE resin was replaced by EMS. The combination of the UPE and EMS resulted in an excellent combination for a new biobased thermoset material with a relatively high elastic modulus and a constant glass transition temperature with up to 25 wt % replacement with EMS. The Izod impact strength was almost constant while the amount of EMS was changed.

Original language	English
Pages (from-to)	698-704
Number of pages	7
Journal	Journal of Polymer Science Part B: Polymer Physics
Volume	45
Issue number	6
DOIs	https://doi.org/10.1002/polb.21059
State	Published - Mar 15 2007

Keywords

Biopolymers
Crosslinking
Dynamic mechanical analysis
Phase separation
Unsaturated polyesters

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10.1002/polb.21059

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title = "Novel biobased resins from blends of functionalized soybean oil and unsaturated polyester resin",

abstract = "Biobased unsaturated polyester (UPE) materials containing epoxidized methyl soyate (EMS) were processed with cobalt naphthenate as a promoter and 2-butanone peroxide as an initiator. A certain amount of the UPE resin was replaced by EMS. The combination of the UPE and EMS resulted in an excellent combination for a new biobased thermoset material with a relatively high elastic modulus and a constant glass transition temperature with up to 25 wt \% replacement with EMS. The Izod impact strength was almost constant while the amount of EMS was changed.",

keywords = "Biopolymers, Crosslinking, Dynamic mechanical analysis, Phase separation, Unsaturated polyesters",

author = "Hiroaki Miyagawa and Mohanty, \{Amar K.\} and Rigoberto Burgue{\~n}o and Drzal, \{Lawrence T.\} and Manjusri Misra",

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doi = "10.1002/polb.21059",

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T1 - Novel biobased resins from blends of functionalized soybean oil and unsaturated polyester resin

AU - Miyagawa, Hiroaki

AU - Mohanty, Amar K.

AU - Burgueño, Rigoberto

AU - Drzal, Lawrence T.

AU - Misra, Manjusri

PY - 2007/3/15

Y1 - 2007/3/15

N2 - Biobased unsaturated polyester (UPE) materials containing epoxidized methyl soyate (EMS) were processed with cobalt naphthenate as a promoter and 2-butanone peroxide as an initiator. A certain amount of the UPE resin was replaced by EMS. The combination of the UPE and EMS resulted in an excellent combination for a new biobased thermoset material with a relatively high elastic modulus and a constant glass transition temperature with up to 25 wt % replacement with EMS. The Izod impact strength was almost constant while the amount of EMS was changed.

AB - Biobased unsaturated polyester (UPE) materials containing epoxidized methyl soyate (EMS) were processed with cobalt naphthenate as a promoter and 2-butanone peroxide as an initiator. A certain amount of the UPE resin was replaced by EMS. The combination of the UPE and EMS resulted in an excellent combination for a new biobased thermoset material with a relatively high elastic modulus and a constant glass transition temperature with up to 25 wt % replacement with EMS. The Izod impact strength was almost constant while the amount of EMS was changed.

KW - Biopolymers

KW - Crosslinking

KW - Dynamic mechanical analysis

KW - Phase separation

KW - Unsaturated polyesters

UR - https://www.scopus.com/pages/publications/33947587275

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DO - 10.1002/polb.21059

M3 - Article

AN - SCOPUS:33947587275

SN - 0887-6266

VL - 45

SP - 698

EP - 704

JO - Journal of Polymer Science Part B: Polymer Physics

JF - Journal of Polymer Science Part B: Polymer Physics

IS - 6

ER -

Novel biobased resins from blends of functionalized soybean oil and unsaturated polyester resin

Abstract

Keywords

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