Orthorhombic A1C60: A conducting linear alkali fulleride polymer?

S. Pekker; L. Forró; L. Mihály; A. Jánossy

doi:10.1016/0038-1098(94)90796-X

Orthorhombic A₁C₆₀: A conducting linear alkali fulleride polymer?

S. Pekker
, L. Forró
, L. Mihály
, A. Jánossy

Physics and Astronomy

Wigner Research Centre for Physics
Swiss Federal Institute of Technology Lausanne
Budapest University of Technology and Economics

Research output: Contribution to journal › Article › peer-review

202 Scopus citations

Abstract

We suggest that the orthorhombic phases of the alkali fullerides, o-A₁C₆₀ (A=K, Rb, Cs), are linear polyners formed in the solid state at about 400 K by a [2+2] cycloaddition reaction between the fulleride ions of the fcc high temperature phase. The electronic structure of the linear polymers is quasi-one-dimensional.

Original language	English
Pages (from-to)	349-352
Number of pages	4
Journal	Solid State Communications
Volume	90
Issue number	6
DOIs	https://doi.org/10.1016/0038-1098(94)90796-X
State	Published - May 1994

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title = "Orthorhombic A1C60: A conducting linear alkali fulleride polymer?",

abstract = "We suggest that the orthorhombic phases of the alkali fullerides, o-A1C60 (A=K, Rb, Cs), are linear polyners formed in the solid state at about 400 K by a [2+2] cycloaddition reaction between the fulleride ions of the fcc high temperature phase. The electronic structure of the linear polymers is quasi-one-dimensional.",

author = "S. Pekker and L. Forr{\'o} and L. Mih{\'a}ly and A. J{\'a}nossy",

year = "1994",

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T2 - A conducting linear alkali fulleride polymer?

AU - Pekker, S.

AU - Forró, L.

AU - Mihály, L.

AU - Jánossy, A.

PY - 1994/5

Y1 - 1994/5

N2 - We suggest that the orthorhombic phases of the alkali fullerides, o-A1C60 (A=K, Rb, Cs), are linear polyners formed in the solid state at about 400 K by a [2+2] cycloaddition reaction between the fulleride ions of the fcc high temperature phase. The electronic structure of the linear polymers is quasi-one-dimensional.

AB - We suggest that the orthorhombic phases of the alkali fullerides, o-A1C60 (A=K, Rb, Cs), are linear polyners formed in the solid state at about 400 K by a [2+2] cycloaddition reaction between the fulleride ions of the fcc high temperature phase. The electronic structure of the linear polymers is quasi-one-dimensional.

UR - https://www.scopus.com/pages/publications/0028433812

U2 - 10.1016/0038-1098(94)90796-X

DO - 10.1016/0038-1098(94)90796-X

M3 - Article

AN - SCOPUS:0028433812

SN - 0038-1098

VL - 90

SP - 349

EP - 352

JO - Solid State Communications

JF - Solid State Communications

IS - 6

ER -

Orthorhombic A₁C₆₀: A conducting linear alkali fulleride polymer?

Abstract

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