Oxidation of chiral 9-fluorinated substrates by castor stearoyl-ACP7 Δ9 desaturase yields novel products

B. Behrouzian; B. Dawson; P. H. Buist; J. Shanklin

doi:10.1039/b100035g

Oxidation of chiral 9-fluorinated substrates by castor stearoyl-ACP7 Δ⁹ desaturase yields novel products

B. Behrouzian
, B. Dawson
, P. H. Buist
, J. Shanklin

Biochemistry and Cell Biology

Carleton University

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Desaturation of (S)-9-fluorostearoyl-ACP using stearoyl-ACP Δ⁹ desaturase yielded mainly (E)-9-fluoroalk-9-enic product, while desaturation of (R)-9-fluorostearoyl-ACP gave the novel (Z)-9-fluoroalk-9-ene and (Z)-9-fluoroalk-10-ene.

Original language	English
Pages (from-to)	765-766
Number of pages	2
Journal	Chemical Communications
Issue number	8
DOIs	https://doi.org/10.1039/b100035g
State	Published - Apr 21 2001

Access to Document

10.1039/b100035g

Cite this

@article{27cb651fc413418980adee70bc423576,

title = "Oxidation of chiral 9-fluorinated substrates by castor stearoyl-ACP7 Δ9 desaturase yields novel products",

abstract = "Desaturation of (S)-9-fluorostearoyl-ACP using stearoyl-ACP Δ9 desaturase yielded mainly (E)-9-fluoroalk-9-enic product, while desaturation of (R)-9-fluorostearoyl-ACP gave the novel (Z)-9-fluoroalk-9-ene and (Z)-9-fluoroalk-10-ene.",

author = "B. Behrouzian and B. Dawson and Buist, \{P. H.\} and J. Shanklin",

year = "2001",

month = apr,

day = "21",

doi = "10.1039/b100035g",

language = "English",

pages = "765--766",

journal = "Chemical Communications",

issn = "1359-7345",

number = "8",

}

TY - JOUR

T1 - Oxidation of chiral 9-fluorinated substrates by castor stearoyl-ACP7 Δ9 desaturase yields novel products

AU - Behrouzian, B.

AU - Dawson, B.

AU - Buist, P. H.

AU - Shanklin, J.

PY - 2001/4/21

Y1 - 2001/4/21

N2 - Desaturation of (S)-9-fluorostearoyl-ACP using stearoyl-ACP Δ9 desaturase yielded mainly (E)-9-fluoroalk-9-enic product, while desaturation of (R)-9-fluorostearoyl-ACP gave the novel (Z)-9-fluoroalk-9-ene and (Z)-9-fluoroalk-10-ene.

AB - Desaturation of (S)-9-fluorostearoyl-ACP using stearoyl-ACP Δ9 desaturase yielded mainly (E)-9-fluoroalk-9-enic product, while desaturation of (R)-9-fluorostearoyl-ACP gave the novel (Z)-9-fluoroalk-9-ene and (Z)-9-fluoroalk-10-ene.

UR - https://www.scopus.com/pages/publications/0035926086

U2 - 10.1039/b100035g

DO - 10.1039/b100035g

M3 - Article

AN - SCOPUS:0035926086

SN - 1359-7345

SP - 765

EP - 766

JO - Chemical Communications

JF - Chemical Communications

IS - 8

ER -

Oxidation of chiral 9-fluorinated substrates by castor stearoyl-ACP7 Δ⁹ desaturase yields novel products

Abstract

Access to Document

Other files and links

Fingerprint

Cite this