Palladium-catalyzed stille couplings of aryl-, vinyl-, and alkyltrichlorostannanes in aqueous solution

Roopa Rai; Katherine B. Aubrecht; David B. Collum

doi:10.1016/0040-4039(95)00485-U

Palladium-catalyzed stille couplings of aryl-, vinyl-, and alkyltrichlorostannanes in aqueous solution

Roopa Rai
, Katherine B. Aubrecht
, David B. Collum

Chemistry

Cornell University

Research output: Contribution to journal › Article › peer-review

94 Scopus citations

Abstract

Stille coupling of water-soluble aryl and vinyl halides with alkyl-, aryl-, and vinyltrichlorostannane derivatives (RSnCl₃) are effected in aqueous solution using a catalyst generated in situ from PdCl₂ and KOH both with and without added PhP(m-C₆H₄SO₃Na)₂. The yields are generally good to excellent, although some limitations of the protocol are described.

Original language	English
Pages (from-to)	3111-3114
Number of pages	4
Journal	Tetrahedron Letters
Volume	36
Issue number	18
DOIs	https://doi.org/10.1016/0040-4039(95)00485-U
State	Published - May 1 1995

Keywords

alkyltrichlorostannanes
aqueous
palladium catalysis
Stille coupling

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10.1016/0040-4039(95)00485-U

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title = "Palladium-catalyzed stille couplings of aryl-, vinyl-, and alkyltrichlorostannanes in aqueous solution",

abstract = "Stille coupling of water-soluble aryl and vinyl halides with alkyl-, aryl-, and vinyltrichlorostannane derivatives (RSnCl3) are effected in aqueous solution using a catalyst generated in situ from PdCl2 and KOH both with and without added PhP(m-C6H4SO3Na)2. The yields are generally good to excellent, although some limitations of the protocol are described.",

keywords = "alkyltrichlorostannanes, aqueous, palladium catalysis, Stille coupling",

author = "Roopa Rai and Aubrecht, \{Katherine B.\} and Collum, \{David B.\}",

year = "1995",

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doi = "10.1016/0040-4039(95)00485-U",

language = "English",

volume = "36",

pages = "3111--3114",

journal = "Tetrahedron Letters",

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TY - JOUR

T1 - Palladium-catalyzed stille couplings of aryl-, vinyl-, and alkyltrichlorostannanes in aqueous solution

AU - Rai, Roopa

AU - Aubrecht, Katherine B.

AU - Collum, David B.

PY - 1995/5/1

Y1 - 1995/5/1

N2 - Stille coupling of water-soluble aryl and vinyl halides with alkyl-, aryl-, and vinyltrichlorostannane derivatives (RSnCl3) are effected in aqueous solution using a catalyst generated in situ from PdCl2 and KOH both with and without added PhP(m-C6H4SO3Na)2. The yields are generally good to excellent, although some limitations of the protocol are described.

AB - Stille coupling of water-soluble aryl and vinyl halides with alkyl-, aryl-, and vinyltrichlorostannane derivatives (RSnCl3) are effected in aqueous solution using a catalyst generated in situ from PdCl2 and KOH both with and without added PhP(m-C6H4SO3Na)2. The yields are generally good to excellent, although some limitations of the protocol are described.

KW - alkyltrichlorostannanes

KW - aqueous

KW - palladium catalysis

KW - Stille coupling

UR - https://www.scopus.com/pages/publications/0028944048

U2 - 10.1016/0040-4039(95)00485-U

DO - 10.1016/0040-4039(95)00485-U

M3 - Article

AN - SCOPUS:0028944048

SN - 0040-4039

VL - 36

SP - 3111

EP - 3114

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 18

ER -

Palladium-catalyzed stille couplings of aryl-, vinyl-, and alkyltrichlorostannanes in aqueous solution

Abstract

Keywords

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