Particle size and albedo effects on emissivity spectra of lunar analog minerals and rocks in the intermediate infrared region

Visible/near-infrared (VNIR) and thermal infrared (TIR) spectroscopy have been widely used to detect and characterize the abundances of silicates across the solar system. Recently, intermediate infrared (IMIR) reflectance spectroscopy (∼4 - 6 μm) has been proposed as a tool to quantify the Mg# in olivine and pyroxene with varying iron, magnesium and calcium content. The lunar surface is composed of rocks with mixed particle sizes and thus quantifying the effects of particle size is extremely important to increase the robustness of IMIR spectroscopy as a tool for lunar surface exploration. Similarly, space weathering has been known to cause optical darkening and affect the spectra of the lunar surface materials across a broad wavelength range. In this study, we have identified the emission features of lunar analog minerals/rocks and their variations with changes in particle sizes and albedo at IMIR wavelengths in simulated lunar environment (SLE). We find that the lunar analog minerals display an increase in emissivity and striking decrease in feature contrast with an increase in particle sizes or decrease in albedo. This study shows that while this wavelength range works well in reflectance space for sample characterization, using it for emissivity measurements via orbital remote sensing or in-situ rovers requires extensive study.