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Phthalocyanine- and calixarene-templating effect on the catalytic performance of solid supported vanadates

  • Grigoriy Sereda
  • , Taejin Kim
  • , Aubrey Jones
  • , Hari Khatri
  • , Christopher L. Marshall
  • , H. Subramanian
  • , Ranjit T. Koodali
  • University of South Dakota
  • Argonne National Laboratory

Research output: Contribution to journalArticlepeer-review

4 Scopus citations

Abstract

Catalytic performance of solid supported monovanadate catalysts toward oxidation of propane is significantly affected by the templating effect of: (1) pretreatment of the solid support with calixarene derivatives before deposition of ammonium vanadate, (2) direct deposition of vanadyl phthalocyanine as the vanadate precursor. This effect is believed to be linked to the accessibility of the active sites, and was studied in comparison with a reference mesoporous support.

Original languageEnglish
Pages (from-to)1086-1096
Number of pages11
JournalCatalysis Letters
Volume141
Issue number8
DOIs
StatePublished - Aug 2011

Keywords

  • Catalysis
  • Heterogeneous catalysis
  • Oxidation
  • Supported catalysts

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