Processing-structure-mechanical property relationships of semicrystalline polyolefin-based block copolymers

Fanny Deplace; Zhigang Wang; Nathaniel Lynd; Atsushi Hotta; Jeffrey Rose; Philip Hustad; Jun Tian; Hisashi Ohtaki; Geoffrey Coates; Fumihiko Shimizu; Kousou Hirokane; Fumiyoshi Yamada; Yong Woo Shin; Lixia Rong; Jie Zhu; Shigeyuki Toki; Benjamin Hsiao; Glenn Fredrickson; Edward Kramer

doi:10.1002/polb.21969

Processing-structure-mechanical property relationships of semicrystalline polyolefin-based block copolymers

Fanny Deplace
, Zhigang Wang
, Nathaniel Lynd
, Atsushi Hotta
, Jeffrey Rose
, Philip Hustad
, Jun Tian
, Hisashi Ohtaki
, Geoffrey Coates
, Fumihiko Shimizu
, Kousou Hirokane
, Fumiyoshi Yamada
, Yong Woo Shin
, Lixia Rong
, Jie Zhu
, Shigeyuki Toki
, Benjamin Hsiao
, Glenn Fredrickson
, Edward Kramer

Chemistry

University of California at Santa Barbara
Cornell University
Mitsubishi Chemical Holdings Corporation
Stony Brook University

Research output: Contribution to journal › Article › peer-review

44 Scopus citations

Abstract

The incremental plastic deformation of the crystals of block copolymers made of semicrystalline polypropylene endblocks and amorphous ethylene-r-propylene midblocks occurring during step cycle tensile tests has dramatic effects on the stress-strain curves. This can be understood from the evolution of the morphology and of the microstructure of the crystalline blocks revealed by X-ray scattering experiments.

Original language	English
Pages (from-to)	1428-1437
Number of pages	10
Journal	Journal of Polymer Science Part B: Polymer Physics
Volume	48
Issue number	13
DOIs	https://doi.org/10.1002/polb.21969
State	Published - Jul 1 2010

Keywords

Block copolymers
Elastomers
Mechanical properties
Polyolefins
Saxs
Thermoplastics
Waxs

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10.1002/polb.21969

Cite this

Deplace, F., Wang, Z., Lynd, N., Hotta, A., Rose, J., Hustad, P., Tian, J., Ohtaki, H., Coates, G., Shimizu, F., Hirokane, K., Yamada, F., Shin, Y. W., Rong, L., Zhu, J., Toki, S., Hsiao, B., Fredrickson, G., & Kramer, E. (2010). Processing-structure-mechanical property relationships of semicrystalline polyolefin-based block copolymers. Journal of Polymer Science Part B: Polymer Physics, 48(13), 1428-1437. https://doi.org/10.1002/polb.21969

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title = "Processing-structure-mechanical property relationships of semicrystalline polyolefin-based block copolymers",

abstract = "The incremental plastic deformation of the crystals of block copolymers made of semicrystalline polypropylene endblocks and amorphous ethylene-r-propylene midblocks occurring during step cycle tensile tests has dramatic effects on the stress-strain curves. This can be understood from the evolution of the morphology and of the microstructure of the crystalline blocks revealed by X-ray scattering experiments.",

keywords = "Block copolymers, Elastomers, Mechanical properties, Polyolefins, Saxs, Thermoplastics, Waxs",

author = "Fanny Deplace and Zhigang Wang and Nathaniel Lynd and Atsushi Hotta and Jeffrey Rose and Philip Hustad and Jun Tian and Hisashi Ohtaki and Geoffrey Coates and Fumihiko Shimizu and Kousou Hirokane and Fumiyoshi Yamada and Shin, \{Yong Woo\} and Lixia Rong and Jie Zhu and Shigeyuki Toki and Benjamin Hsiao and Glenn Fredrickson and Edward Kramer",

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doi = "10.1002/polb.21969",

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Deplace, F, Wang, Z, Lynd, N, Hotta, A, Rose, J, Hustad, P, Tian, J, Ohtaki, H, Coates, G, Shimizu, F, Hirokane, K, Yamada, F, Shin, YW, Rong, L, Zhu, J, Toki, S, Hsiao, B, Fredrickson, G & Kramer, E 2010, 'Processing-structure-mechanical property relationships of semicrystalline polyolefin-based block copolymers', Journal of Polymer Science Part B: Polymer Physics, vol. 48, no. 13, pp. 1428-1437. https://doi.org/10.1002/polb.21969

TY - JOUR

T1 - Processing-structure-mechanical property relationships of semicrystalline polyolefin-based block copolymers

AU - Deplace, Fanny

AU - Wang, Zhigang

AU - Lynd, Nathaniel

AU - Hotta, Atsushi

AU - Rose, Jeffrey

AU - Hustad, Philip

AU - Tian, Jun

AU - Ohtaki, Hisashi

AU - Coates, Geoffrey

AU - Shimizu, Fumihiko

AU - Hirokane, Kousou

AU - Yamada, Fumiyoshi

AU - Shin, Yong Woo

AU - Rong, Lixia

AU - Zhu, Jie

AU - Toki, Shigeyuki

AU - Hsiao, Benjamin

AU - Fredrickson, Glenn

AU - Kramer, Edward

PY - 2010/7/1

Y1 - 2010/7/1

N2 - The incremental plastic deformation of the crystals of block copolymers made of semicrystalline polypropylene endblocks and amorphous ethylene-r-propylene midblocks occurring during step cycle tensile tests has dramatic effects on the stress-strain curves. This can be understood from the evolution of the morphology and of the microstructure of the crystalline blocks revealed by X-ray scattering experiments.

AB - The incremental plastic deformation of the crystals of block copolymers made of semicrystalline polypropylene endblocks and amorphous ethylene-r-propylene midblocks occurring during step cycle tensile tests has dramatic effects on the stress-strain curves. This can be understood from the evolution of the morphology and of the microstructure of the crystalline blocks revealed by X-ray scattering experiments.

KW - Block copolymers

KW - Elastomers

KW - Mechanical properties

KW - Polyolefins

KW - Saxs

KW - Thermoplastics

KW - Waxs

UR - https://www.scopus.com/pages/publications/77952978149

U2 - 10.1002/polb.21969

DO - 10.1002/polb.21969

M3 - Article

AN - SCOPUS:77952978149

SN - 0887-6266

VL - 48

SP - 1428

EP - 1437

JO - Journal of Polymer Science Part B: Polymer Physics

JF - Journal of Polymer Science Part B: Polymer Physics

IS - 13

ER -

Processing-structure-mechanical property relationships of semicrystalline polyolefin-based block copolymers

Abstract

Keywords

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