Protective Fabrics: Metal-Organic Framework Textiles for Rapid Photocatalytic Sulfur Mustard Simulant Detoxification

Dennis T. Lee; Jovenal D. Jamir; Gregory W. Peterson; Gregory N. Parsons

doi:10.1016/j.matt.2019.11.005

Protective Fabrics: Metal-Organic Framework Textiles for Rapid Photocatalytic Sulfur Mustard Simulant Detoxification

Dennis T. Lee
, Jovenal D. Jamir
, Gregory W. Peterson
, Gregory N. Parsons

Materials Science and Engineering

North Carolina State University
U.S. Army CCDC Chemical and Biological Center

Research output: Contribution to journal › Article › peer-review

138 Scopus citations

Abstract

Earth-abundant Al-based metal-organic frameworks (MOFs) are shown for the first time to rapidly neutralize a toxic vesicant simulant via catalytic oxidation. A unique metal oxide coordination replication approach facilitates integration of the active MOF film onto commercial non-woven textile in a conformal and well-adhered coating. Under visible light, this chemical protective composite material enables extremely fast vesicant simulant detoxification compared with the same MOFs in conventional powder form, indicating its promising practical implementation against hazardous chemicals.

Original language	English
Pages (from-to)	404-415
Number of pages	12
Journal	Matter
Volume	2
Issue number	2
DOIs	https://doi.org/10.1016/j.matt.2019.11.005
State	Published - Feb 5 2020

Keywords

MAP4: Demonstrate
MOF-fiber composite
atomic layer deposition
chemical warfare agent simulants
photocatalysis
protective fabrics

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10.1016/j.matt.2019.11.005

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title = "Protective Fabrics: Metal-Organic Framework Textiles for Rapid Photocatalytic Sulfur Mustard Simulant Detoxification",

abstract = "Earth-abundant Al-based metal-organic frameworks (MOFs) are shown for the first time to rapidly neutralize a toxic vesicant simulant via catalytic oxidation. A unique metal oxide coordination replication approach facilitates integration of the active MOF film onto commercial non-woven textile in a conformal and well-adhered coating. Under visible light, this chemical protective composite material enables extremely fast vesicant simulant detoxification compared with the same MOFs in conventional powder form, indicating its promising practical implementation against hazardous chemicals.",

keywords = "MAP4: Demonstrate, MOF-fiber composite, atomic layer deposition, chemical warfare agent simulants, photocatalysis, protective fabrics",

author = "Lee, \{Dennis T.\} and Jamir, \{Jovenal D.\} and Peterson, \{Gregory W.\} and Parsons, \{Gregory N.\}",

note = "Publisher Copyright: {\textcopyright} 2019 Elsevier Inc.",

year = "2020",

month = feb,

day = "5",

doi = "10.1016/j.matt.2019.11.005",

language = "English",

volume = "2",

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journal = "Matter",

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TY - JOUR

T1 - Protective Fabrics

T2 - Metal-Organic Framework Textiles for Rapid Photocatalytic Sulfur Mustard Simulant Detoxification

AU - Lee, Dennis T.

AU - Jamir, Jovenal D.

AU - Peterson, Gregory W.

AU - Parsons, Gregory N.

PY - 2020/2/5

Y1 - 2020/2/5

N2 - Earth-abundant Al-based metal-organic frameworks (MOFs) are shown for the first time to rapidly neutralize a toxic vesicant simulant via catalytic oxidation. A unique metal oxide coordination replication approach facilitates integration of the active MOF film onto commercial non-woven textile in a conformal and well-adhered coating. Under visible light, this chemical protective composite material enables extremely fast vesicant simulant detoxification compared with the same MOFs in conventional powder form, indicating its promising practical implementation against hazardous chemicals.

AB - Earth-abundant Al-based metal-organic frameworks (MOFs) are shown for the first time to rapidly neutralize a toxic vesicant simulant via catalytic oxidation. A unique metal oxide coordination replication approach facilitates integration of the active MOF film onto commercial non-woven textile in a conformal and well-adhered coating. Under visible light, this chemical protective composite material enables extremely fast vesicant simulant detoxification compared with the same MOFs in conventional powder form, indicating its promising practical implementation against hazardous chemicals.

KW - MAP4: Demonstrate

KW - MOF-fiber composite

KW - atomic layer deposition

KW - chemical warfare agent simulants

KW - photocatalysis

KW - protective fabrics

UR - https://www.scopus.com/pages/publications/85078678655

U2 - 10.1016/j.matt.2019.11.005

DO - 10.1016/j.matt.2019.11.005

M3 - Article

AN - SCOPUS:85078678655

SN - 2590-2393

VL - 2

SP - 404

EP - 415

JO - Matter

JF - Matter

IS - 2

ER -

Protective Fabrics: Metal-Organic Framework Textiles for Rapid Photocatalytic Sulfur Mustard Simulant Detoxification

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Keywords

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