Reaction of trimethylsilyl cyanide with carbodiimides

Iwao Ojima; Shin Ichi Inaba; Yoichiro Nagai

doi:10.1016/S0022-328X(00)86374-3

Reaction of trimethylsilyl cyanide with carbodiimides

Iwao Ojima
, Shin Ichi Inaba
, Yoichiro Nagai

Chemistry

Sagami Chemical Research Institute
Gunma University

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Trimethylsilyl cyanidereact with carbodiimides in the presence of aluminum trichloride to give 1 1 adducts, N-trimethylsilyl-1-cyanoformamidines (I), in high yields. At rather high temperatures (150-200 °C) the reaction also proceeded without catalyst. The 1 1 adduct reacted with isocyanates and carbodiimides forming 4,5-diiminodiazolidine-2-one and 2,4,5-triiminoimidazolidine, respectively.

Original language	English
Pages (from-to)	C5-C7
Journal	Journal of Organometallic Chemistry
Volume	99
Issue number	1
DOIs	https://doi.org/10.1016/S0022-328X(00)86374-3
State	Published - Oct 7 1975

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title = "Reaction of trimethylsilyl cyanide with carbodiimides",

abstract = "Trimethylsilyl cyanidereact with carbodiimides in the presence of aluminum trichloride to give 1 1 adducts, N-trimethylsilyl-1-cyanoformamidines (I), in high yields. At rather high temperatures (150-200 °C) the reaction also proceeded without catalyst. The 1 1 adduct reacted with isocyanates and carbodiimides forming 4,5-diiminodiazolidine-2-one and 2,4,5-triiminoimidazolidine, respectively.",

author = "Iwao Ojima and Inaba, \{Shin Ichi\} and Yoichiro Nagai",

year = "1975",

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T1 - Reaction of trimethylsilyl cyanide with carbodiimides

AU - Ojima, Iwao

AU - Inaba, Shin Ichi

AU - Nagai, Yoichiro

PY - 1975/10/7

Y1 - 1975/10/7

N2 - Trimethylsilyl cyanidereact with carbodiimides in the presence of aluminum trichloride to give 1 1 adducts, N-trimethylsilyl-1-cyanoformamidines (I), in high yields. At rather high temperatures (150-200 °C) the reaction also proceeded without catalyst. The 1 1 adduct reacted with isocyanates and carbodiimides forming 4,5-diiminodiazolidine-2-one and 2,4,5-triiminoimidazolidine, respectively.

AB - Trimethylsilyl cyanidereact with carbodiimides in the presence of aluminum trichloride to give 1 1 adducts, N-trimethylsilyl-1-cyanoformamidines (I), in high yields. At rather high temperatures (150-200 °C) the reaction also proceeded without catalyst. The 1 1 adduct reacted with isocyanates and carbodiimides forming 4,5-diiminodiazolidine-2-one and 2,4,5-triiminoimidazolidine, respectively.

UR - https://www.scopus.com/pages/publications/49549142108

U2 - 10.1016/S0022-328X(00)86374-3

DO - 10.1016/S0022-328X(00)86374-3

M3 - Article

AN - SCOPUS:49549142108

SN - 0022-328X

VL - 99

SP - C5-C7

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -

Reaction of trimethylsilyl cyanide with carbodiimides

Abstract

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