Reactions of phosphine-substituted alkylidyne carbonyltungsten complexes with dithiocarbamate ligands: Phosphine substitution and alkylidyne- carbonyl coupling

Andreas Mayr; Richard T. Chang; Lee Tsung-Yi; Ki Cheung On; Michael A. Kjelsberg; Gregory A. McDermott; Donna Van Engen

doi:10.1016/0022-328X(94)84090-3

Reactions of phosphine-substituted alkylidyne carbonyltungsten complexes with dithiocarbamate ligands: Phosphine substitution and alkylidyne- carbonyl coupling

Andreas Mayr
, Richard T. Chang
, Lee Tsung-Yi
, Ki Cheung On
, Michael A. Kjelsberg
, Gregory A. McDermott
, Donna Van Engen

Chemistry

Stony Brook University
Princeton University

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Reaction of the alkylidyne tungsten complexes cis- and trans- [W(CPh)Cl(CO)₂(PMe₃)₂] with sodium diethyldithiocarbamate affords the ketenyl complex [W(OCCPh)(S₂CNEt₂)(CO)(PMe₃)₂]. Reaction of [W(CPh)Cl(CO)(PMe₃)₃] with diethyldithiocarbamate gives the dithiocarbamate-substituted alkylidyne tungsten complex [W(CPh)(S₂CNEt₂)(CO)(PMe₃)₂]. Reaction of cis-[W(CPh)Cl(CO) ₂(PPh₃)₂] with sodium dimethyldithiocarbamate leads to substitution of PPh₃ and formation of [W(CPh)(S₂CNMe₂)(CO)₂ (PPh₃)]. The solid state structure of [W(CPh)(S₂CNEt2)(CO)(PMe₃)₂] was determined by X-ray crystallography. Reaction of [W(CPh) (S₂CNEt₂)(CO)(Me₃)₂] with carbon monoxide in solution as well as in the solid state affords [W(OCCPh)(₂CNEt2)(CO)(PMe₃) ₂]. Pyrolysis of [W(OCCPh)(S₂CNEt₂)(CO)(PMe₃)₂] at 100°C in toluene solution gives [W(CPh)(S₂CNEt₂)(CO)(PMe₃) ₂].

Original language	English
Pages (from-to)	47-53
Number of pages	7
Journal	Journal of Organometallic Chemistry
Volume	479
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(94)84090-3
State	Published - Oct 4 1994

Keywords

Alkylidyne complexes
Coupling reactions
Ketenyl
Phosphines
Tungsten

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10.1016/0022-328X(94)84090-3

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@article{21ec8e2e8ede43b288fe5390bfe18109,

title = "Reactions of phosphine-substituted alkylidyne carbonyltungsten complexes with dithiocarbamate ligands: Phosphine substitution and alkylidyne- carbonyl coupling",

abstract = "Reaction of the alkylidyne tungsten complexes cis- and trans- [W(CPh)Cl(CO)2(PMe3)2] with sodium diethyldithiocarbamate affords the ketenyl complex [W(OCCPh)(S2CNEt2)(CO)(PMe3)2]. Reaction of [W(CPh)Cl(CO)(PMe3)3] with diethyldithiocarbamate gives the dithiocarbamate-substituted alkylidyne tungsten complex [W(CPh)(S2CNEt2)(CO)(PMe3)2]. Reaction of cis-[W(CPh)Cl(CO) 2(PPh3)2] with sodium dimethyldithiocarbamate leads to substitution of PPh3 and formation of [W(CPh)(S2CNMe2)(CO)2 (PPh3)]. The solid state structure of [W(CPh)(S2CNEt2)(CO)(PMe3)2] was determined by X-ray crystallography. Reaction of [W(CPh) (S2CNEt2)(CO)(Me3)2] with carbon monoxide in solution as well as in the solid state affords [W(OCCPh)(2CNEt2)(CO)(PMe3) 2]. Pyrolysis of [W(OCCPh)(S2CNEt2)(CO)(PMe3)2] at 100°C in toluene solution gives [W(CPh)(S2CNEt2)(CO)(PMe3) 2].",

keywords = "Alkylidyne complexes, Coupling reactions, Ketenyl, Phosphines, Tungsten",

author = "Andreas Mayr and Chang, \{Richard T.\} and Lee Tsung-Yi and On, \{Ki Cheung\} and Kjelsberg, \{Michael A.\} and McDermott, \{Gregory A.\} and \{Van Engen\}, Donna",

year = "1994",

month = oct,

day = "4",

doi = "10.1016/0022-328X(94)84090-3",

language = "English",

volume = "479",

pages = "47--53",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

number = "1-2",

}

TY - JOUR

T1 - Reactions of phosphine-substituted alkylidyne carbonyltungsten complexes with dithiocarbamate ligands

T2 - Phosphine substitution and alkylidyne- carbonyl coupling

AU - Mayr, Andreas

AU - Chang, Richard T.

AU - Tsung-Yi, Lee

AU - On, Ki Cheung

AU - Kjelsberg, Michael A.

AU - McDermott, Gregory A.

AU - Van Engen, Donna

PY - 1994/10/4

Y1 - 1994/10/4

N2 - Reaction of the alkylidyne tungsten complexes cis- and trans- [W(CPh)Cl(CO)2(PMe3)2] with sodium diethyldithiocarbamate affords the ketenyl complex [W(OCCPh)(S2CNEt2)(CO)(PMe3)2]. Reaction of [W(CPh)Cl(CO)(PMe3)3] with diethyldithiocarbamate gives the dithiocarbamate-substituted alkylidyne tungsten complex [W(CPh)(S2CNEt2)(CO)(PMe3)2]. Reaction of cis-[W(CPh)Cl(CO) 2(PPh3)2] with sodium dimethyldithiocarbamate leads to substitution of PPh3 and formation of [W(CPh)(S2CNMe2)(CO)2 (PPh3)]. The solid state structure of [W(CPh)(S2CNEt2)(CO)(PMe3)2] was determined by X-ray crystallography. Reaction of [W(CPh) (S2CNEt2)(CO)(Me3)2] with carbon monoxide in solution as well as in the solid state affords [W(OCCPh)(2CNEt2)(CO)(PMe3) 2]. Pyrolysis of [W(OCCPh)(S2CNEt2)(CO)(PMe3)2] at 100°C in toluene solution gives [W(CPh)(S2CNEt2)(CO)(PMe3) 2].

AB - Reaction of the alkylidyne tungsten complexes cis- and trans- [W(CPh)Cl(CO)2(PMe3)2] with sodium diethyldithiocarbamate affords the ketenyl complex [W(OCCPh)(S2CNEt2)(CO)(PMe3)2]. Reaction of [W(CPh)Cl(CO)(PMe3)3] with diethyldithiocarbamate gives the dithiocarbamate-substituted alkylidyne tungsten complex [W(CPh)(S2CNEt2)(CO)(PMe3)2]. Reaction of cis-[W(CPh)Cl(CO) 2(PPh3)2] with sodium dimethyldithiocarbamate leads to substitution of PPh3 and formation of [W(CPh)(S2CNMe2)(CO)2 (PPh3)]. The solid state structure of [W(CPh)(S2CNEt2)(CO)(PMe3)2] was determined by X-ray crystallography. Reaction of [W(CPh) (S2CNEt2)(CO)(Me3)2] with carbon monoxide in solution as well as in the solid state affords [W(OCCPh)(2CNEt2)(CO)(PMe3) 2]. Pyrolysis of [W(OCCPh)(S2CNEt2)(CO)(PMe3)2] at 100°C in toluene solution gives [W(CPh)(S2CNEt2)(CO)(PMe3) 2].

KW - Alkylidyne complexes

KW - Coupling reactions

KW - Ketenyl

KW - Phosphines

KW - Tungsten

UR - https://www.scopus.com/pages/publications/0003020205

U2 - 10.1016/0022-328X(94)84090-3

DO - 10.1016/0022-328X(94)84090-3

M3 - Article

AN - SCOPUS:0003020205

SN - 0022-328X

VL - 479

SP - 47

EP - 53

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

Reactions of phosphine-substituted alkylidyne carbonyltungsten complexes with dithiocarbamate ligands: Phosphine substitution and alkylidyne- carbonyl coupling

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Keywords

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